88824-89-9Relevant articles and documents
A concise, stereocontrolled synthesis of spectinomycin
Cuny, Eckehard,Lichtenthaler, Frieder W.
, p. 1120 - 1124 (2007/10/03)
A simple and concise synthesis of the antibiotic spectinomycin is described. The key step comprises a reaction cascade initiated by the β-selective 5-O-glycosylation of an N,N-blocked myo-1,3-inosadiamine 10 with a suitable actinospectosyl donor-the d-glu
Sugar Enolones, XIX. - An Approach to Actinospectose-Type 2,3-Diketo Sugars. - Synthetic Proof for the R Configuration of "Herzgift-Methylreduktinase"
Lichtenthaler, Frieder W.,Loehe, Albert,Cuny, Eckehard
, p. 1973 - 1985 (2007/10/02)
A stereochemically defined, preparatively satisfactory access is described to stable derivatives of D-actinospectose, a 4,6-dideoxy-D-glycero-hexopyranos-2,3-diulose (3a 3b) realized in spectinomycin (1) and a series of Calotropis cardenolides (2).Key