methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

Base Information

Chemical Name:methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside
CAS No.:122713-82-0
Molecular Formula:C₁₆H₂₁F₃O₇S
Molecular Weight:414.4
Hs Code.:

Synonyms:methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

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Chemical Property of methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

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Technology Process of methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

There total 10 articles about methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 122713-81-9
methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-α-L-xylo-hexopyranoside

: 122713-82-0
methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

Guidance literature:: With pyridine; In 1,2-dichloro-ethane; at -20 - 0 ℃;
DOI:10.1016/0008-6215(89)80056-4

Reference yield:

: 122713-75-1
methyl 2-O-allyl-α-L-fucopyranoside

: 122713-82-0
methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / dibutyltin oxide, Bu₄NI / benzene / Heating

2: 88.8 percent / NaH / diethyl ether / Heating

3: 73 percent / tributylstannane, α,α'-azodiisobutanonitrile / benzene / 0.33 h / Heating

4: 76.4 percent / KOCMe₃ / dimethylsulfoxide / 0.25 h / 100 °C

5: HgO, HgCl₂ / acetone; H₂O

6: 93 percent / pyridine / 1,2-dichloro-ethane / -20 - 0 °C

With pyridine; 2,2'-azobis(isobutyronitrile); potassium tert-butylate; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydride; di(n-butyl)tin oxide; mercury dichloride; mercury(II) oxide; In diethyl ether; water; dimethyl sulfoxide; 1,2-dichloro-ethane; acetone; benzene;
DOI:10.1016/0008-6215(89)80056-4

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 122713-82-0
methyl 4,6-dideoxy-3-O-(4-methoxybenzyl)-2-O-(trifluoromethylsulfonyl)-α-L-xylo-hexopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / dibutyltin oxide, Bu₄NI / benzene / Heating

2: 88.8 percent / NaH / diethyl ether / Heating

3: 73 percent / tributylstannane, α,α'-azodiisobutanonitrile / benzene / 0.33 h / Heating

4: 76.4 percent / KOCMe₃ / dimethylsulfoxide / 0.25 h / 100 °C

5: HgO, HgCl₂ / acetone; H₂O

6: 93 percent / pyridine / 1,2-dichloro-ethane / -20 - 0 °C

With pyridine; 2,2'-azobis(isobutyronitrile); potassium tert-butylate; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydride; di(n-butyl)tin oxide; mercury dichloride; mercury(II) oxide; In diethyl ether; water; dimethyl sulfoxide; 1,2-dichloro-ethane; acetone; benzene;
DOI:10.1016/0008-6215(89)80056-4