<1'-13C>-1',1'-Dibrom-methylidencyclohexan

Base Information

• Chemical Name: <1'-13C>-1',1'-Dibrom-methylidencyclohexan
• CAS No.: 86127-94-8
• Molecular Formula: C₇H₁₀Br₂
• Molecular Weight: 254.953
• Mol file: 86127-94-8.mol

Synonyms:<1'-13C>-1',1'-Dibrom-methylidencyclohexan

Chemical Property of <1'-13C>-1',1'-Dibrom-methylidencyclohexan

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of <1'-13C>-1',1'-Dibrom-methylidencyclohexan

There total 1 articles about <1'-13C>-1',1'-Dibrom-methylidencyclohexan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.5%

carbon-13C-tetrabromide (72802-79-0) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → <1'-13C>-1',1'-Dibrom-methylidencyclohexan (86127-94-8)

Guidance literature:

With triphenylphosphine; In benzene; at 80 ℃; for 14h;

DOI:10.1002/hlca.19830660128

Reference yield:

<1'-13C>-1',1'-Dibrom-methylidencyclohexan (86127-94-8) → C6(13)CH10Br(6)Li

Guidance literature:

With [⁽⁶⁾Li]-n-butyllithium; In various solvent(s); at -123 ℃;

DOI:10.1002/hlca.19830660128

Reference yield:

<1'-13C>-1',1'-Dibrom-methylidencyclohexan (86127-94-8) → <1'-13C>-1'-Brommethylidencyclohexan (86127-79-9)

Guidance literature:

With methanol; n-butyllithium; Yield given. Multistep reaction; 1.) THF, -105 deg C, 10 min; 2.) -105 - -100 deg C;

DOI:10.1002/hlca.19830660128

upstream raw materials:

carbon-¹³C-tetrabromide

cyclohexanone

Downstream raw materials:

<1'-13C>-1'-Brommethylidencyclohexan