[Re2Cl4(μ-bis(diphenylphosphino)methane)2]

Base Information

Chemical Name:[Re2Cl4(μ-bis(diphenylphosphino)methane)2]
CAS No.:58298-10-5
Molecular Formula:C₅₀H₄₄Cl₄P₄Re₂
Molecular Weight:1283.02
Hs Code.:

Synonyms:[Re2Cl4(μ-bis(diphenylphosphino)methane)2]

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Chemical Property of [Re2Cl4(μ-bis(diphenylphosphino)methane)2]

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Technology Process of [Re2Cl4(μ-bis(diphenylphosphino)methane)2]

There total 14 articles about [Re2Cl4(μ-bis(diphenylphosphino)methane)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 14705-94-3,29131-21-3
cis-dirhenium diacetate tetrachloride dihydrate

: 2071-20-7
bis-diphenylphosphinomethane

: 58298-10-5
[Re2Cl4(μ-bis(diphenylphosphino)methane)2]

Guidance literature:: In ethanol; by refluxing ethanol soln. contg. cis-Re2(μ-O2CCH3)2Cl4(H2O)2 and bis(diphenylphosphino)methane for 18 h under N2;
DOI:10.1016/S0020-1693(00)00321-2

Reference yield: 90.0%

: Re₂Cl₆(P(n-Bu)3)2

: 2071-20-7
bis-diphenylphosphinomethane

: 58298-10-5
Re₂Cl₄(bis(diphenylphosphino)methane)2

Guidance literature:: In methanol; addn. of methanol to a mixt. of rhenium complex and diphosphine, refluxing for 3 h; decantation, washing ppt. with methanol, Et2O, drying in vac.;
DOI:10.1039/b304509a

Reference yield: 87.0%

: Re₂Cl₆(P(n-Bu)3)2

: 2071-20-7
bis-diphenylphosphinomethane

: 58298-10-5
[Re2Cl4(μ-bis(diphenylphosphino)methane)2]

Guidance literature:: In methanol; a mixt. of Re2Cl6(PBu3)2 and dppm is added to methanol and refluxed for 0.5 h; purple solid is filtered and washed with ether, recrystn.;