C₁₄H₁₃NO

Base Information

• Chemical Name: C₁₄H₁₃NO
• CAS No.: 1428264-96-3
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.263
• Mol file: 1428264-96-3.mol

Synonyms:C₁₄H₁₃NO

Chemical Property of C₁₄H₁₃NO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₁₄H₁₃NO

There total 1 articles about C₁₄H₁₃NO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-oxobutyraldehyde (625-34-3) + 2-amino-5-methylbiphenyl (42308-28-1) → C14H13NO (1428264-96-3)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.201206115

Reference yield:

C14H13NO (1428264-96-3) → 2‐methyl‐6‐phenylphenanthridine

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine; trichlorophosphate / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

2: manganese(III) acetylacetonate / toluene / 1 h / 80 °C / Inert atmosphere

With manganese(III) acetylacetonate; triethylamine; trichlorophosphate; In tetrahydrofuran; toluene;

DOI:10.1002/anie.201206115

Reference yield:

C14H13NO (1428264-96-3) → (2‐methylphenanthridin‐6‐yl)diphenylphosphine oxide (1507941-20-9)

Guidance literature:

Multi-step reaction with 2 steps

1: trichlorophosphate; triethylamine / tetrahydrofuran / 2 h / 0 °C / Schlenk technique; Inert atmosphere

2: triethylamine; Diphenyliodonium triflate / dichloromethane / 5 h / 40 °C / Schlenk technique; Inert atmosphere

With Diphenyliodonium triflate; triethylamine; trichlorophosphate; In tetrahydrofuran; dichloromethane;

DOI:10.1021/acs.orglett.6b02983

upstream raw materials:

3-oxobutyraldehyde

2-amino-5-methylbiphenyl

Downstream raw materials:

3’-methylphenanthridine

6-(4-methoxyphenyl)-2-methylphenanthridine

2-methyl-6-(4-(trifluoromethyl)phenyl)phenanthridine

methyl 4-(2-methylphenanthridin-6-yl)benzoate

Refernces