all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2}

Base Information

• Chemical Name: all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2}
• CAS No.: 125540-48-9
• Molecular Formula: C₈H₁₀Br₂IrO₆*C₃₆H₃₀NP₂
• Molecular Weight: 1092.78
• Mol file: 125540-48-9.mol

Synonyms:all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2}

Chemical Property of all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2}

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2}

There total 1 articles about all cis-{(Ph₃P)2}{IrBr₂(CO)2(CH₂CO₂Me)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate (56557-01-8) + bromoacetic acid methyl ester (96-32-2) → all cis-{(Ph3P)2}{IrBr2(CO)2(CH2CO2Me)2} (125540-48-9)

Guidance literature:

In tetrahydrofuran; byproducts: carbon monoxide; (N2); dry solvents; addn. of org. compd. in THF to Ir-compd., after 3 h react. terminated (IR-spectroscopic monitoring); evapn. to dryness in vac., treatment of residue (Et2O), filtration, washing (isopropyl alcohol), crystn. by addn. of mixt. (hexane/Et2O 80:20) into chloroform soln. of product; elem. anal.;

DOI:10.1021/om00118a006

Reference yield: 80.0%

all cis-{(Ph3P)2}{IrBr2(CO)2(CH2CO2Me)2} (125540-48-9) → trans-IrBr(OC){P(C6H5)3}2 (15842-08-7)

Guidance literature:

With triphenylphosphine; In ethanol; byproducts: carbon monoxide, ((C6H5)3P)2NBr, methyl acetate; (N2); dry solvent; refluxing suspn. of PPh3 and Ir-compd. in EtOH (5 h), pptn.; filtration, washing (hot EtOH); elem. anal.;

DOI:10.1021/om00118a006

upstream raw materials:

{bis(triphenylphosphine)nitrogen(1+)} tetracarbonyliridate

bromoacetic acid methyl ester

Downstream raw materials:

trans-IrBr(OC){P(C₆H₅)3}2