[gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)]

Base Information

• Chemical Name: [gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)]
• CAS No.: 1383851-05-5
• Molecular Formula: C₃₀H₃₁AuClN
• Molecular Weight: 638.002
• Mol file: 1383851-05-5.mol

Synonyms:[gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)]

Chemical Property of [gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)]

Chemical Property:

Purity/Quality:

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• Hazard Codes: 

MSDS Files:

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Technology Process of [gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)]

There total 2 articles about [gold(I)Cl(1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + 3,5-bis(2',6'-dimethylphenyl)-1-mesitylpyridin-1-ium trifluoromethanesulfonate (1383851-01-1) → [gold(I)Cl(1-(2,4,6-Me3C6H2)-3,5-di(2,6-Me2C6H3) 2-pyridylidene)] (1383851-05-5)

Guidance literature:

3,5-bis(2',6'-dimethylphenyl)-1-mesitylpyridin-1-ium trifluoromethanesulfonate; With tetrabutyl-ammonium chloride; silver(l) oxide; In 1,2-dichloro-ethane; at 20 ℃; Inert atmosphere;

chloro(dimethylsulfide) gold(I); In 1,2-dichloro-ethane; at 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.3762/bjoc.11.295

Reference yield: 27.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + 1-(2,4,6-Me3C6H2)-3,5-di(2,6-Me2C6H3) 2-pyridylidene (1383851-03-3) → [gold(I)Cl(1-(2,4,6-Me3C6H2)-3,5-di(2,6-Me2C6H3) 2-pyridylidene)] (1383851-05-5)

Guidance literature:

In tetrahydrofuran; 1,3,5-triaryl 2-pyridylidene reacted with Me2SAuCl in THF at room temp.;

DOI:10.1039/c2cc33184e

Reference yield: 99.0%

(Dichloroiodo)benzene (932-72-9) + [gold(I)Cl(1-(2,4,6-Me3C6H2)-3,5-di(2,6-Me2C6H3) 2-pyridylidene)] (1383851-05-5) → [3,5-bis(2,6-dimethylphenyl)-1-mesityl-pyridylidene]gold trichloride

Guidance literature:

In dichloromethane; at 20 ℃; for 19h; Inert atmosphere;

DOI:10.3762/bjoc.11.295

upstream raw materials:

chloro(dimethylsulfide) gold(I)

1-(2,4,6-Me₃C₆H₂)-3,5-di(2,6-Me₂C₆H₃) 2-pyridylidene

3,5-bis(2',6'-dimethylphenyl)-1-mesitylpyridin-1-ium trifluoromethanesulfonate