bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt

Base Information

• Chemical Name: bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt
• CAS No.: 631869-32-4
• Molecular Formula: C₂₉H₃₅CoFN₄O₄P
• Molecular Weight: 612.587
• Mol file: 631869-32-4.mol

Synonyms:bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt

Chemical Property of bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt

Chemical Property:

Purity/Quality:

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Technology Process of bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt

There total 1 articles about bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

chlorobis(dimethylglyoximato)(triphenylphosphine)cobalt (23295-34-3) + 1-Bromo-3-fluoropropane (352-91-0) → bis(dimethylglyoximato)(triphenylphosphine)(3-fluoropropyl)cobalt (631869-32-4)

Guidance literature:

With NaOH; NaBH₄; In methanol; under Ar; soln. of NaBH4 in methanolic NaOH added dropwise to soln. of CoCl(dmgH)2(PPh3) in methanolic NaOH, stirred at room temp. for 1-2 h, soln. of BrCH2CH2CH2F in MeOH added dropwise, stirred for 45 min; water added, mixt. neutralized (pH 7-8) with solid CO2, after 30 min ppt. filtered off, washed with water and Et2O, dried under vac.; elem. anal.;

DOI:10.1021/om030525a

upstream raw materials:

chlorobis(dimethylglyoximato)(triphenylphosphine)cobalt

1-Bromo-3-fluoropropane