(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Base Information

Chemical Name:(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside
CAS No.:250584-40-8
Molecular Formula:C₂₁H₃₂O₉
Molecular Weight:428.48
Hs Code.:

Synonyms:(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Suppliers and Price of (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

There total 7 articles about (6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 217325-00-3
methyl (methyl-3-O-benzyl-2-O-methoxymethyl-4-C-(hydroxy-(2,2-dimethyl[1,3]dioxolan-4-yl)methyl)-α-D-xylo/β-L-arabinofuranoside) uronate

: 250584-40-8
(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 2h;
DOI:10.1016/S0040-4020(99)00637-7

Reference yield:

: methyl (methyl-3-O-benzyl-α,β-D-xylofuranoside) uronate

: 250584-40-8
(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: iPr₂NEt / CH₂Cl₂ / 168000 h / 20 °C

2: 66 percent / KHMDS; CeCl₃ / toluene; tetrahydrofuran / -100 - -20 °C

3: 68 percent / LiAlH₄ / diethyl ether / 2 h / 20 °C

With lithium aluminium tetrahydride; cerium(III) chloride; potassium hexamethylsilazane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; toluene; 1: Alkylation / 2: Condensation / 3: Reduction;
DOI:10.1016/S0040-4020(99)00637-7

Reference yield:

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 250584-40-8
(6R)-methyl-3-O-benzyl-2-O-methoxymethyl-4-C-hydroxymethyl-6,7-O-isopropyl-α-D-galacto/α-D-gluco/β-L-altrofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 66 percent / KHMDS; CeCl₃ / toluene; tetrahydrofuran / -100 - -20 °C

2: 68 percent / LiAlH₄ / diethyl ether / 2 h / 20 °C

With lithium aluminium tetrahydride; cerium(III) chloride; potassium hexamethylsilazane; In tetrahydrofuran; diethyl ether; toluene; 1: Condensation / 2: Reduction;
DOI:10.1016/S0040-4020(99)00637-7