Technology Process of 1,1,6-Trimethyl-1,2-dihydronaphthalene
There total 15 articles about 1,1,6-Trimethyl-1,2-dihydronaphthalene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrachloromethane; N-Bromosuccinimide; dibenzoyl peroxide;
DOI:10.1021/ja01152a089
- Guidance literature:
-
With
toluene-4-sulfonic acid; calcium chloride;
In
cyclohexane;
at 50 ℃;
for 2h;
DOI:10.1021/acs.jafc.9b01428
- Guidance literature:
-
Multi-step reaction with 6 steps
1: aluminum (III) chloride / Milling
2: hydrogenchloride / water / 4 h / 20 °C
3: trimethylsilyl trifluoromethanesulfonate / dichloromethane; hexane / 15 h / 0 - 20 °C / Inert atmosphere
4: trifluoroacetic acid; trifluoroacetic anhydride / 4 h / 0 - 20 °C
5: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / 0.5 h / 20 °C
6: calcium chloride; toluene-4-sulfonic acid / cyclohexane / 2 h / 50 °C
With
hydrogenchloride; aluminum (III) chloride; sodium tetrahydroborate; trimethylsilyl trifluoromethanesulfonate; cerium(III) chloride heptahydrate; toluene-4-sulfonic acid; trifluoroacetic acid; trifluoroacetic anhydride; calcium chloride;
In
methanol; hexane; dichloromethane; cyclohexane; water;
1: |Friedel-Crafts Acylation;
DOI:10.1021/acs.jafc.9b01428