Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

Base Information

Chemical Name:Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆
CAS No.:59560-54-2
Molecular Formula:C₄₁H₄₀NNiP₂S₂*F₆P
Molecular Weight:876.509
Hs Code.:

Ni(P(C<sub>6</sub>H<sub>5</sub>)3)2(S<sub>2</sub>CN(C<sub>2</sub>H<sub>5</sub>)2)<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>=[Ni(P(C<sub>6</sub>H<sub>5</sub>)3)2(S<sub>2</sub>CN(C<sub>2</sub>H<sub>5</sub>)2)]PF<sub>6</sub>

Synonyms:Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

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Chemical Property of Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

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Technology Process of Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

There total 3 articles about Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 30052-07-4
{NiCl(diethyldithiocarbamate)(PPh₃)}

: 59560-54-2
Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

Guidance literature:: With triphenylphosphine; In acetone; byproducts: AgCl; addn. of AgPF6 to mixt. of Ni-complex and PPh3; filtration off of AgCl, crystn. on hexane addn., collection, recrystn. (CH2Cl2/hexane);
DOI:10.1039/DT9760000541

Reference yield: 25.0%

: 55060-09-8
tris(diethyldithiocarbamato)nickel(IV) hexafluorophosphate

: 59560-54-2
Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

: nickel diethyldithiocarbamate

Guidance literature:: With triphenylphosphine; In dichloromethane; byproducts: Ph3PS, [Ph3P(C(NMe2)S)]PF6; >=2 equiv. of PPh3, stirring for 30 min; evapn. or pptn. on hexane addn., filtration off of Ni(S2CNEt2), crystn. on Et2O addn., collection, washing (Et2O), recrystn. (CH2Cl2/hexane), drying (80°C, 2 h); yield depending on educt ratio;
DOI:10.1039/DT9760000541

Reference yield:

: 17084-13-8
potassium hexafluorophosphate

: 30052-07-4
{NiCl(diethyldithiocarbamate)(PPh₃)}

: 59560-54-2
Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Ni(P(C₆H₅)3)2(S₂CN(C₂H₅)2)]PF₆

Guidance literature:: With triphenylphosphine; In acetone; addn. of KPF6 to mixt, of Ni-complex and PPh3; evapn., extn. into CH2Cl2, crystn. on addn. of light petroleum, collection, recrystn. (CH2Cl2/hexane), drying (80°C, 2 h);
DOI:10.1039/DT9760000541