diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

Base Information

Chemical Name:diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane
CAS No.:1394167-01-1
Molecular Formula:C₁₇H₂₆OSi
Molecular Weight:274.478
Hs Code.:

Synonyms:diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

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Chemical Property of diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

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Technology Process of diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

There total 5 articles about diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₇H₂₇IOSi

: diethyl(3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

: 1394167-01-1
diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; for 0.666667h; Overall yield = 208 mg; Inert atmosphere;
DOI:10.1021/ol3018853

Reference yield:

: tert-butyl ((S)-3-methyl-4-(oxiran-2-yl)butoxy)diphenylsilane

: diethyl(3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

: 1394167-01-1
diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

Guidance literature:: Multi-step reaction with 4 steps

1: 2,2,6,6-tetramethyl-piperidine; n-butyllithium / tert-butyl methyl ether; hexane / 16 h / 0 °C / Inert atmosphere

2: ammonium fluoride / methanol / 20 h / 20 °C / Inert atmosphere

3: 1H-imidazole; iodine; triphenylphosphine / water; acetonitrile / 0.5 h / 0 °C / Inert atmosphere

4: potassium tert-butylate / tetrahydrofuran / 0.67 h / 0 - 20 °C / Inert atmosphere

With 2,2,6,6-tetramethyl-piperidine; 1H-imidazole; ammonium fluoride; n-butyllithium; potassium tert-butylate; iodine; triphenylphosphine; In tetrahydrofuran; methanol; hexane; tert-butyl methyl ether; water; acetonitrile;
DOI:10.1021/ol3018853

Reference yield:

: 17876-59-4
chloro(diethyl)(phenyl)silane

: diethyl(3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

: 1394167-01-1
diethyl((2S,3S)-3-((R)-2-methylbut-3-en-1-yl)oxiran-2-yl)(phenyl)silane

Guidance literature:: Multi-step reaction with 4 steps

1: 2,2,6,6-tetramethyl-piperidine; n-butyllithium / tert-butyl methyl ether; hexane / 16 h / 0 °C / Inert atmosphere

2: ammonium fluoride / methanol / 20 h / 20 °C / Inert atmosphere

3: 1H-imidazole; iodine; triphenylphosphine / water; acetonitrile / 0.5 h / 0 °C / Inert atmosphere

4: potassium tert-butylate / tetrahydrofuran / 0.67 h / 0 - 20 °C / Inert atmosphere

With 2,2,6,6-tetramethyl-piperidine; 1H-imidazole; ammonium fluoride; n-butyllithium; potassium tert-butylate; iodine; triphenylphosphine; In tetrahydrofuran; methanol; hexane; tert-butyl methyl ether; water; acetonitrile;
DOI:10.1021/ol3018853