Chloro(diethyl)phenylsilane

Base Information

• Chemical Name: Chloro(diethyl)phenylsilane
• CAS No.: 17876-59-4
• Molecular Formula: C10H15 Cl Si
• Molecular Weight: 198.768
• NSC Number: 139847
• DSSTox Substance ID: DTXSID80300893
• Nikkaji Number: J696.637C
• Wikidata: Q82044312
• Mol file: 17876-59-4.mol

Synonyms:17876-59-4;chloro(diethyl)phenylsilane;NSC139847;chlorodiethylphenylsilane;SCHEMBL703207;DTXSID80300893;NSC-139847

Chemical Property of Chloro(diethyl)phenylsilane

Chemical Property:

• Vapor Pressure: 0.0712mmHg at 25°C
• Boiling Point: 236.8°C at 760 mmHg
• Flash Point: 88.9°C
• Density: 0.97g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 198.0631547
• Heavy Atom Count: 12
• Complexity: 126

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](CC)(C1=CC=CC=C1)Cl

Technology Process of Chloro(diethyl)phenylsilane

There total 6 articles about Chloro(diethyl)phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

triethylsilyl chloride (994-30-9) + diphenylsilyl dichloride (80-10-4) → chloro(diethyl)(phenyl)silane (17876-59-4) + chloro(ethyl)(diphenyl)silane (18407-41-5) + dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5)

Guidance literature:

With aluminum (III) chloride; at 120 ℃; for 3h; Overall yield = 60 %;

DOI:10.1134/S1070363215030111

Reference yield:

dichloro(ethyl)phenylsilane (1125-27-5,18447-29-5) + triethylaluminum (97-93-8) → chloro(diethyl)(phenyl)silane (17876-59-4)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; tricyclohexylphosphine; In 1,4-dioxane; at 120 ℃; for 24h;

DOI:10.1002/cctc.201900047

Reference yield:

triethylaluminum (97-93-8) + Phenyltrichlorosilane (98-13-5) → chloro(diethyl)(phenyl)silane (17876-59-4)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; tricyclohexylphosphine; In 1,4-dioxane; at 120 ℃; for 24h;

DOI:10.1002/cctc.201900047

upstream raw materials:

phenyllithium

diethyldichlorosilane

triethylsilyl chloride

diphenylsilyl dichloride

Downstream raw materials:

diethyl-(2-chloro-ethoxy)-phenyl-silane

1,1-diethyl-3,3,3-trimethyl-1-phenyl-disiloxane

1,1-diethyl-1,3,3,3-tetraphenyl-disiloxane

diethyl(phenyl)silanol