C₃₆H₅₈N₄O₇SSi

Base Information

• Chemical Name: C₃₆H₅₈N₄O₇SSi
• CAS No.: 1300655-99-5
• Molecular Formula: C₃₆H₅₈N₄O₇SSi
• Molecular Weight: 719.031
• Mol file: 1300655-99-5.mol

Synonyms:C₃₆H₅₈N₄O₇SSi

Chemical Property of C₃₆H₅₈N₄O₇SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₅₈N₄O₇SSi

There total 18 articles about C₃₆H₅₈N₄O₇SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C29H54O8Si (1300655-98-4) + 1-Phenyl-1H-tetrazole-5-thiol (86-93-1) → C36H58N4O7SSi (1300655-99-5)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; for 24h; Inert atmosphere;

DOI:10.1021/ja201467z

Reference yield:

C13H18O2 (1300655-86-0) → C36H58N4O7SSi (1300655-99-5)

Guidance literature:

Multi-step reaction with 15 steps

1.1: n-butyllithium / hexane; tert-butyl methyl ether / 0.17 h / -78 °C / Inert atmosphere

1.2: 0.67 h / 0 - 20 °C / Inert atmosphere

2.1: sodium hydride / hexane / 2 h / Inert atmosphere; Reflux

3.1: acetylacetonatodicarbonylrhodium(l) / benzene / 4.5 h / 60 °C / 51716.2 Torr / Autoclave

3.2: 1 h / 40 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

5.2: -78 - 20 °C / Inert atmosphere

6.1: toluene / 18 h / Inert atmosphere; Reflux

7.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; citric acid / tetrahydrofuran; tert-butyl alcohol / 24 h / Inert atmosphere

8.1: sodium periodate; sodium hydrogencarbonate / tetrahydrofuran; water / 1 h / 0 °C / Inert atmosphere

9.1: tetra-(n-butyl)ammonium iodide / dichloromethane; water / 3 h / Inert atmosphere

10.1: acetylacetonatodicarbonylrhodium(l); hydrogen; triphenylphosphine / tetrahydrofuran / 24 h / 20 - 50 °C / 25858.1 Torr / Autoclave

11.1: pyridine; dmap / dichloromethane / 16 h / -20 °C / Inert atmosphere

12.1: titanium tetrachloride / dichloromethane / 0.08 h / 0 °C / Inert atmosphere

12.2: 3 h / -40 °C / Inert atmosphere

13.1: dmap / 24 h / Inert atmosphere

14.1: 5% Pd(II)/C(eggshell); hydrogen / tetrahydrofuran / 2 h / 760.05 Torr

15.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 24 h / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; dmap; acetylacetonatodicarbonylrhodium(l); sodium periodate; osmium(VIII) oxide; n-butyllithium; di-isopropyl azodicarboxylate; 5% Pd(II)/C(eggshell); water; hydrogen; titanium tetrachloride; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; triphenylphosphine; citric acid; In tetrahydrofuran; hexane; dichloromethane; tert-butyl methyl ether; water; toluene; tert-butyl alcohol; benzene; 9.1: Felkin addition;

DOI:10.1021/ja201467z

Reference yield:

C32H54O7Si → C36H58N4O7SSi (1300655-99-5)

Guidance literature:

Multi-step reaction with 5 steps

1.1: pyridine; dmap / dichloromethane / 16 h / -20 °C / Inert atmosphere

2.1: titanium tetrachloride / dichloromethane / 0.08 h / 0 °C / Inert atmosphere

2.2: 3 h / -40 °C / Inert atmosphere

3.1: dmap / 24 h / Inert atmosphere

4.1: 5% Pd(II)/C(eggshell); hydrogen / tetrahydrofuran / 2 h / 760.05 Torr

5.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 24 h / Inert atmosphere

With pyridine; dmap; di-isopropyl azodicarboxylate; 5% Pd(II)/C(eggshell); hydrogen; titanium tetrachloride; triphenylphosphine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja201467z

upstream raw materials:

C₁₃H₁₈O₂

C₃₁H₅₂O₆Si

C₃₄H₅₆O₈Si

C₄₁H₆₇NO₇S₂Si

Downstream raw materials:

C₃₆H₅₈N₄O₉SSi