1300655-86-0Relevant academic research and scientific papers
Toward more "ideal" polyketide natural product synthesis: A step-economical synthesis of zincophorin methyl ester
Harrison, Tyler J.,Ho, Stephen,Leighton, James L.
supporting information; experimental part, p. 7308 - 7311 (2011/06/23)
A highly efficient and step-economical synthesis of zincophorin methyl ester has been achieved. The unprecedented step economy of this zincophorin synthesis is principally due to an application of the tandem silylformylation-crotylsilylation/Tamao oxidati
Catalytic asymmetric epoxidation of alkenes with arabinose-derived ketones containing a cyclohexane-1,2-diacetal
Shing, Tony K.M.,Luk, To
experimental part, p. 883 - 886 (2009/09/08)
The effect of diol blocking groups, cyclohexane-1,2-diacetal verses butane-1,2-diacetal, on the asymmetric epoxidation of trans- and cis-alkenes by arabinose-derived ketones is reported. The ketone catalysts with a cyclohexane-1,2-acetal display similar asymmetric induction as those catalysts with a butane-1,2-diacetal in most cases. For (E)-1-benzyloxy-4-hexene, the ee of the enantioselective epoxidation has reached 61% with the cyclohexane-1,2-dineopentyl acetal ketone catalyst.
