(Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1)

Base Information

Chemical Name:(Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1)
CAS No.:14286-61-4
Molecular Formula:C₂₈H₂₂N₄NiO₄
Molecular Weight:537.197
Hs Code.:

Synonyms:Nickel,bis(benzil dioximato)- (8CI); Nickel, bis(diphenylglyoximato)- (6CI,7CI);Nickel, bis[(diphenylethanedione dioximato)(1-)-N,N']-; Nickel,bis[[diphenylethanedione di(oximato-kN)](1-)]- (9CI); Ethanedione, diphenyl-, dioxime,nickel complex; Bis(diphenylethanedione dioximato) nickel;Bis(diphenylglyoximato)nickel; Bis(diphenylglyoximato)nickel (II); NSC 196336

Suppliers and Price of (Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of (Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1)

Chemical Property:

Vapor Pressure:6.85E-07mmHg at 25°C
Boiling Point:393.3°C at 760 mmHg
Flash Point:191.7°C

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1)

There total 2 articles about (Z)-N-hydroxy-2-nitroso-1,2-diphenylethenamine - nickel (2:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 23873-81-6
benzildioxime

: 83864-14-6
nickel dichloride

: 14286-61-4
[Ni(α-benzyl dioxime(-1H))2]

Guidance literature:: In ethanol; water; adding alcoholic soln. of dioxime to aq. soln. of NiCl2; Ppt. was filtered off, washed with EtOH, dried in an oven at 60°C;

Reference yield:

: 373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6
nickel diacetate

: 23873-81-6
benzildioxime

: 14286-61-4
[Ni(α-benzyl dioxime(-1H))2]

Guidance literature:: In ethanol; water; reaction of ligand and metal(II) acetate in soln. of aq. EtOH;

Reference yield: 88.0%

: 14286-61-4
[(C₆H₅)CNON(OH)C(C₆H₅)C(C₆H₅)NON(OH)C(C₆H₅)]Ni

: {(CH₃)2NH₂}⁽¹⁺⁾*B₅O₈^(1-)*2H₂O*(CH₃)2NCHO={(CH₃)2NH₂}B₅O₈*2H₂O*(CH₃)2NCHO

: Mono(dihydroxyboroxino)-bis(diphenylglyoximato)nickel(II)

Guidance literature:: In N,N-dimethyl-formamide; byproducts: dimethylamine; dissoln. in boiling DMF, cooling to 125°C; filtration, boiling the precipitate with DMF, filtration, drying at 120°C, elem. anal.;