4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Base Information

Chemical Name:4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside
CAS No.:187022-27-1
Molecular Formula:C₂₂H₂₆Cl₃NO₁₁
Molecular Weight:586.808
Hs Code.:

Synonyms:4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

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Chemical Property of 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

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Technology Process of 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

There total 1 articles about 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 122210-05-3
1,3,4,6-tetra-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranose

: 150-76-5
4-methoxy-phenol

: 187022-27-1
4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane;
DOI:10.1016/S0008-6215(96)90118-4

Reference yield: 98.0%

: 108-98-5
thiophenol

: 187022-27-1
4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

: 187022-49-7
(2R,3S,4R,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)-5-(((2,2,2-trichloroethoxy)carbonyl)amino)tetrahydro-2H-pyran-3,4-diyl diacetate

Guidance literature:: With boron trifluoride diethyl etherate; In chloroform; at 40 ℃;
DOI:10.1016/S0008-6215(96)90118-4

Reference yield: 60.0%

: 100-39-0
benzyl bromide

: 187022-27-1
4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside

: 1616860-50-4
4-methoxyphenyl N-benzyl-2-amino-2,3-N,O-carbonyl-4,6-di-O-benzyl-2-deoxy-β-Dglucopyranoside

Guidance literature:: 4-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside; With 15-crown-5; sodium hydroxide; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; for 20h; regioselective reaction; Inert atmosphere;
DOI:10.1002/adsc.201400269