(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

Base Information

Chemical Name:(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate
CAS No.:1026162-56-0
Molecular Formula:C₂₃H₃₀O₃Si
Molecular Weight:382.575
Hs Code.:

Synonyms:(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

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Chemical Property of (+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

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Technology Process of (+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

There total 2 articles about (+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: (+/-)-methyl 2-[(but-3-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

: 1026162-56-0
(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

Guidance literature:: (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate; at 0 ℃;
DOI:10.1039/b306920f

Reference yield:

: 121129-31-5
(+/-)-methyl (2-hydroxy-3,3-dimethyl)butyrate

: 1026162-56-0
(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / B(C₆F₅)3

2: 91 percent / [(COD)Ir(PPh₂Me)2](+)*PF₆(-) / 0 °C

With tris(pentafluorophenyl)borate; (1,5-cyclooctadiene)bis(methyldiphenylphosphine) iridium hexafluorophosphate;
DOI:10.1039/b306920f

Reference yield: 90.0%

: 1026162-56-0
(+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate

: (+/-)-2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutanol

Guidance literature:: (+/-)-methyl 2-[(E-but-2-enyl)diphenylsilanyloxy]-3,3-dimethylbutyrate; With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; for 1h;

With tartaric acid; In methanol; dichloromethane; at 20 ℃;
DOI:10.1016/j.tet.2009.01.117