2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:245432-97-7
Molecular Formula:C₁₄H₂₃BO₂
Molecular Weight:234.146
Hs Code.:
Mol file:245432-97-7.mol

Synonyms:2-[(E)-2-(cyclohex-1-en-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Suppliers and Price of 2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
trans-2-(1-Cyclohexenyl)vinylboronic acid pinacol ester 97%
5g
$ 498.00

Sigma-Aldrich
trans-2-(1-Cyclohexenyl)vinylboronic acid pinacol ester 97%
1g
$ 166.00

Crysdot
(E)-2-(2-(cyclohex-1-en-1-yl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
5g
$ 746.00

Chemenu
(E)-2-(2-(cyclohex-1-en-1-yl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95%mixTBCasstabilizer
1g
$ 238.00

Alichem
(E)-2-(2-(cyclohex-1-en-1-yl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1g
$ 400.00

Total 5 raw suppliers

Chemical Property of 2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Refractive Index:n20/D1.505
Flash Point:>110℃
Density:0.963 g/mL at 25 °C
Storage Temp.:2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-2-(1-Cyclohexenyl)vinylboronic acid pinacol ester 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 5 articles about 2-[(1E)-2-(1-Cyclohexen-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 931-49-7
1-ethenylcyclohexene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 245432-97-7
2-[(E)-2-(cyclohex-1-en-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With C₂₈H₄₀CuNO; In acetonitrile; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere;
DOI:10.1016/j.jorganchem.2016.09.025

Reference yield: 93.0%

: 931-49-7
1-ethenylcyclohexene

: 73183-34-3
bis(pinacol)diborane

: 245432-97-7
2-[(E)-2-(cyclohex-1-en-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With methanol; copper (I) tert-butoxide; triphenylphosphine; In tetrahydrofuran; at 20 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201007182

Reference yield: 56.0%

: 1-(2-methoxyvinyl)cyclohex-1-ene

: 73183-34-3
bis(pinacol)diborane

: 245432-97-7
2-[(E)-2-(cyclohex-1-en-1-yl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With bis(acetylacetonate)nickel(II); potassium phosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; zinc; In cyclohexane; toluene; at 120 ℃; for 24h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c02236