1'-benzoyl-N,N-diethyl ferrocenecarboxamide

Base Information

• Chemical Name: 1'-benzoyl-N,N-diethyl ferrocenecarboxamide
• CAS No.: 765307-40-2
• Molecular Formula: C₂₂H₂₃FeNO₂
• Molecular Weight: 389.277
• Mol file: 765307-40-2.mol

Synonyms:1'-benzoyl-N,N-diethyl ferrocenecarboxamide

Chemical Property of 1'-benzoyl-N,N-diethyl ferrocenecarboxamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1'-benzoyl-N,N-diethyl ferrocenecarboxamide

There total 1 articles about 1'-benzoyl-N,N-diethyl ferrocenecarboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1'-iodo-N,N-diethyl ferrocenecarboxamide (765307-20-8) + carbon monoxide (201230-82-2) + triphenylphosphine (603-35-0) → 1'-benzoyl-N,N-diethyl ferrocenecarboxamide (765307-40-2)

Guidance literature:

With sodium tetraphenyl borate; triethylamine; palladium diacetate; In toluene; Fe-contg. compd. (0.25 mmol), NaBPh4 (0.25 mmol), Pd-contg. compd. (0.0125 mmol) and PPh3 (0.025 mmol) were placed into a flask under CO, and Et3N and toluene were added; the mixt. was heated at 90-100°C; after completion of the react. the volatile compds. were removed in vac.; the residue was dissolved in toluene, washed with 5% H3PO4, satd. aq. NaHCO3 and brine, and dried over Na2SO4; chromy. (Al2O3, benzene/EtOAc);elem. anal.;

DOI:10.1016/j.jorganchem.2004.05.046

upstream raw materials:

1'-iodo-N,N-diethyl ferrocenecarboxamide

carbon monoxide

triphenylphosphine