tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

Base Information

Chemical Name:tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate
CAS No.:1285534-63-5
Molecular Formula:C₃₅H₅₁NO₇Si
Molecular Weight:625.878
Hs Code.:

Synonyms:tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

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Chemical Property of tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

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Technology Process of tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

There total 6 articles about tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.1%

: 24424-99-5
di-tert-butyl dicarbonate

: 1285534-62-4
(1E,4E)-1-(4-(methylamino)phenyl)-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-3-one

: 1285534-63-5
tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

Guidance literature:: In tetrahydrofuran; for 48h; Inert atmosphere; Reflux;
DOI:10.1021/jm101404k

Reference yield:

: 1285534-36-2
(E)-4-(4-(methylamino)phenyl)but-3-en-2-one

: 1285534-63-5
tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium methylate / methanol; ethanol / 12 h / 20 °C

2: 1H-imidazole / dichloromethane / 2 h / 20 °C

3: tetrahydrofuran / 48 h / Inert atmosphere; Reflux

With 1H-imidazole; sodium methylate; In tetrahydrofuran; methanol; ethanol; dichloromethane; 1: Claisen condensation;
DOI:10.1021/jm101404k

Reference yield:

: 946-49-6,3490-37-7,30625-98-0
(E)-4-(4-nitrophenyl)-3-buten-2-one

: 1285534-63-5
tert-butyl methyl(4-((1E,4E)-3-oxo-5-(4-((2,2,3,3-tetramethyl-4,7,10-trioxa-3-siladodecan-12-yl)oxy)phenyl)penta-1,4-dien-1-yl)phenyl)carbamate

Guidance literature:: Multi-step reaction with 5 steps

1: hydrogenchloride; tin(ll) chloride / ethanol; water / 2 h / Reflux

2: potassium carbonate / acetone / 8 h / 20 °C

3: sodium methylate / methanol; ethanol / 12 h / 20 °C

4: 1H-imidazole / dichloromethane / 2 h / 20 °C

5: tetrahydrofuran / 48 h / Inert atmosphere; Reflux

With 1H-imidazole; hydrogenchloride; sodium methylate; potassium carbonate; tin(ll) chloride; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; acetone; 3: Claisen condensation;
DOI:10.1021/jm101404k