methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

Base Information

Chemical Name:methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate
CAS No.:1315257-14-7
Molecular Formula:C₂₄H₁₉NO₃
Molecular Weight:369.42
Hs Code.:

Synonyms:methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

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Chemical Property of methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

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Technology Process of methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

There total 3 articles about methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 23754-46-3
methyl 4-(methylaminocarbonyl)benzoate

: 501-65-5
diphenyl acetylene

: 1315257-14-7
methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

Guidance literature:: With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate; In tert-Amyl alcohol; at 100 ℃; for 22h; Inert atmosphere;
DOI:10.1002/anie.201101943

Reference yield:

: 7377-26-6
4-Methoxycarbonylbenzoyl chloride

: 1315257-14-7
methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / diethyl ether / 20 °C

2: [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate / tert-Amyl alcohol / 22 h / 100 °C / Inert atmosphere

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate; potassium carbonate; In tert-Amyl alcohol; diethyl ether;
DOI:10.1002/anie.201101943

Reference yield:

: 1679-64-7
Monomethyl terephthalate

: 1315257-14-7
methyl 2-methyl-1-oxo-3,4-diphenyl-1,2-dihydroisoquinoline-6-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: thionyl chloride / N,N-dimethyl-formamide / 1 h / 80 °C / Inert atmosphere

2: potassium carbonate / diethyl ether / 20 °C

3: [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate / tert-Amyl alcohol / 22 h / 100 °C / Inert atmosphere

With thionyl chloride; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate; potassium carbonate; In tert-Amyl alcohol; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1002/anie.201101943