Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO)

Base Information

• Chemical Name: Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO)
• CAS No.: 88029-50-9
• Molecular Formula: CH₃*C₂H₆OS*C₆H₅*C₁₀H₁₅*Ir
• Molecular Weight: 497.725

Synonyms:Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO)

Chemical Property of Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO)

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Technology Process of Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO)

There total 2 articles about Ir⁽³⁺⁾*CH₃^(1-)*C₅(CH₃)5^(1-)*C₆H₅^(1-)*(CH₃)2SO=C₅(CH₃)5Ir(CH₃)(C₆H₅)((CH₃)2SO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ir(3+)*(C5(CH3)5)(1-)*2CH3(1-)*(CH3)2SO=(C5(CH3)5)Ir(CH3)2((CH3)2SO) → Ir(3+)*CH3(1-)*C5(CH3)5(1-)*C6H5(1-)*(CH3)2SO=C5(CH3)5Ir(CH3)(C6H5)((CH3)2SO) (88029-50-9)

Guidance literature:

With benzene; In benzene; byproducts: CH4; heating;

DOI:10.1039/c39830000825

Reference yield:

Ir(3+)*(C5(CH3)5)(1-)*2CH3(1-)*(CH3)2SO=(C5(CH3)5)Ir(CH3)2((CH3)2SO) + benzene-d6 (1076-43-3) → Ir(3+)*CH3(1-)*C5(CH3)5(1-)*C6H5(1-)*(CH3)2SO=C5(CH3)5Ir(CH3)(C6H5)((CH3)2SO) (88029-50-9) + Ir(3+)*C5(CH3)5(1-)*CH3(1-)*C6(2)H5(1-)*(CH3)2SO=(C5(CH3)5)Ir(CH3)(C6(2)H5)((CH3)2SO) (88029-49-6)

Guidance literature:

With benzene; In not given; byproducts: CH4, CH3D;

DOI:10.1039/c39830000825

Reference yield: 95.0%

Ir(3+)*CH3(1-)*C5(CH3)5(1-)*C6H5(1-)*(CH3)2SO=C5(CH3)5Ir(CH3)(C6H5)((CH3)2SO) (88029-50-9) → (pentamethylcyclopentadienyl)(carbonyl)(methyl)(phenyl)iridium

Guidance literature:

With carbon monoxide; In cyclohexane; byproducts: Me2SO; 5 atm CO, 60°C, 15 h; solvent removal, extn. (wet pentane), drying, concn., crystn.;

DOI:10.1016/0022-328X(85)80349-1

upstream raw materials:

benzene-d6

Downstream raw materials:

Cp*Ir(CO)(Ph)₂

C₅(CH₃)5Ir(CH₃)(C₆H₄CH₃)(CO)

C₅(CH₃)5Ir(C₆H₅)(C₆H₄CH₃)(CO)

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