2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine

Base Information

• Chemical Name: 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine
• CAS No.: 604806-71-5
• Molecular Formula: C₂₃H₃₀N₂
• Molecular Weight: 334.505
• Mol file: 604806-71-5.mol

Synonyms:2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine

Chemical Property of 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine

There total 1 articles about 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-((2,6-diisopropylphenyl)imino)pentan-2-one (471247-65-1) + aniline hydrochloride (142-04-1,36663-09-9) → 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine (604806-71-5)

Guidance literature:

In ethanol; for 24h; Reflux;

DOI:10.1039/c2dt12176j

Reference yield: 83.0%

samarium(III) chloride + Na(NHC6H3-2,6-(i-Pr)2) + 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine (604806-71-5) → [(2,6-iPr2C6H3)NC(Me)CHC(Me)N(C6H5)]-2SmNH(2,6-iPr2C6H3)

Guidance literature:

2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine; With sodium hydride; In tetrahydrofuran; Inert atmosphere; Schlenk technique;

samarium(III) chloride; In tetrahydrofuran; at 60 ℃; for 24h; Inert atmosphere; Schlenk technique;

Na(NHC₆H₃-2,6-(i-Pr)2); In tetrahydrofuran; at 20 ℃; for 48h;

DOI:10.1002/aoc.3150

Reference yield: 82.0%

bis(bis(trimethylsilyl)amido)zinc(II) + 2-(2,6-diisopropylphenyl)aminopent-4-ene-4-(phenyl)imine (604806-71-5) → (CH(C(CH3)N)2(C6H3(CH(CH3)2)2)(C6H5))Zn(N(Si(CH3)3)2) (1085283-26-6)

Guidance literature:

In benzene; under Ar atm. soln. Zn(N(SiMe3)2)2 and ligand in benzene was heated at 70°C for 18 h; solvent was removed in vacuo, residue was washed with hexane; elem. anal.;

DOI:10.1021/om800597f

upstream raw materials:

4-((2,6-diisopropylphenyl)imino)pentan-2-one

aniline hydrochloride

Downstream raw materials:

[(CH(CH₃)2)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₅]Al(C₂H₅)2

[(cyclopentadienyl)Cr(II)(2,6-(Me₂CH)2C₆H₃NC(Me)CH(Me)NPh)]

(CH(C(CH₃)N)2(C₆H₃(CH(CH₃)2)2)(C₆H₅))Zn(N(Si(CH₃)3)2)

[(cyclopentadienyl)Cr(III)Cl(2,6-(Me₂CH)2C₆H₃NC(Me)CH(Me)NPh)]