RuH(OCOPh)(CO)(PPh₃)2

Base Information

Chemical Name:RuH(OCOPh)(CO)(PPh₃)2
CAS No.:100514-75-8
Molecular Formula:C₄₄H₃₆O₃P₂Ru
Molecular Weight:775.786
Hs Code.:

Synonyms:RuH(OCOPh)(CO)(PPh₃)2

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Chemical Property of RuH(OCOPh)(CO)(PPh₃)2

Chemical Property:

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Technology Process of RuH(OCOPh)(CO)(PPh₃)2

There total 9 articles about RuH(OCOPh)(CO)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 65-85-0,8013-63-6
benzoic acid

: 100514-75-8
RuH(OCOPh)(CO)(PPh₃)2

Guidance literature:: (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); With potassium hydroxide; In butan-1-ol; at 125 ℃; for 1h;

benzoic acid; In butan-1-ol; for 1h; Heating / reflux;

Reference yield:

: 25360-32-1,22337-78-6
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)

: 100514-75-8
hydridoruthenium(carbonyl)bis(triphenylphosphine)(OCOC₅H₅)

Guidance literature:: With bencoic acid; In 2-methoxy-ethanol; Under oxygen-free N2 a suspn. of hydrido complex in 2-methoxyethanol is refluxed, to the boiling suspn. is added carboxylic acid, refluxing.; elem. anal.;
DOI:10.1016/0022-328X(89)85011-9

Reference yield:

: 100-52-7
benzaldehyde

: 100514-75-8
RuH(OCOPh)(CO)(PPh₃)2

Guidance literature:: Multi-step reaction with 2 steps

1: potassium hydroxide / toluene / 1 h / 120 °C / Schlenk technique; Inert atmosphere

2: dichloromethane / 6 h / 20 °C / Schlenk technique; Inert atmosphere

With potassium hydroxide; In dichloromethane; toluene; 1: |Cannizzaro Reaction;
DOI:10.1039/c9dt01414d