1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene

Base Information

• Chemical Name: 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene
• CAS No.: 656252-74-3
• Molecular Formula: C₂₆H₄₈O₂Si₂
• Molecular Weight: 448.837

Synonyms:1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene

Chemical Property of 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene

Chemical Property:

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Technology Process of 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene

There total 3 articles about 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tert-butyldimethylsilyl chloride (18162-48-6) + 2-(2-hydroxymethyl-benzyl)-hex-5-en-1-ol (656251-92-2) → 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene (656252-74-3)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1021/ja030498f

Reference yield:

methyl 5-hexenoate (2396-80-7) → 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene (656252-74-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: LDA

1.3: DIBAL-H

2.1: 91 percent / DMAP; Et₃N / CH₂Cl₂ / 24 h / 20 °C

With dmap; triethylamine; lithium diisopropyl amide; In dichloromethane;

DOI:10.1021/ja030498f

Reference yield:

2-(bromomethyl)benzonitrile (22115-41-9) → 1-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-dimethyl-silanyloxymethyl)-hex-5-enyl]-benzene (656252-74-3)

Guidance literature:

Multi-step reaction with 2 steps

1.1: LDA

1.3: DIBAL-H

2.1: 91 percent / DMAP; Et₃N / CH₂Cl₂ / 24 h / 20 °C

With dmap; triethylamine; lithium diisopropyl amide; In dichloromethane;

DOI:10.1021/ja030498f

upstream raw materials:

tert-butyldimethylsilyl chloride

2-(2-hydroxymethyl-benzyl)-hex-5-en-1-ol

methyl 5-hexenoate

2-(bromomethyl)benzonitrile

Downstream raw materials:

6-(tert-butyl-dimethyl-silanyloxymethyl)-7-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-3-hydroxy-2-methoxy-3-methyl-heptanoic acid methyl ester

5-(tert-butyl-dimethyl-silanyloxymethyl)-6-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-hexan-2-one

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