2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Base Information

Chemical Name:2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)
CAS No.:321868-67-1
Molecular Formula:C₁₆H₂₀O₄S₂
Molecular Weight:340.464
Hs Code.:

Synonyms:2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Suppliers and Price of 2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

There total 3 articles about 2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 75-15-0,12122-00-8
carbon disulfide

: 18439-39-9
2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]-dioxol-(6S)-ol

: 74-88-4
methyl iodide

: 321868-67-1
2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Guidance literature:: 2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]-dioxol-(6S)-ol; With sodium hydride; In tetrahydrofuran; hexane; at 0 ℃; for 0.25h;

carbon disulfide; In tetrahydrofuran; hexane; at 0 ℃; for 0.25h;

methyl iodide; In tetrahydrofuran; hexane; at 0 - 20 ℃;
DOI:10.1016/S0957-4166(00)00389-X

Reference yield:

: phenylmagnesium bromide

: 321868-67-1
2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Guidance literature:: Multi-step reaction with 2 steps

1.1: 83 percent / tetrahydrofuran / 20 °C

2.1: NaH / tetrahydrofuran; hexane / 0.25 h / 0 °C

2.2: tetrahydrofuran; hexane / 0.25 h / 0 °C

2.3: 93 percent / tetrahydrofuran; hexane / 0 - 20 °C

With sodium hydride; In tetrahydrofuran; hexane; 1.1: Substitution / 2.1: Metallation / 2.2: Addition / 2.3: Methylation;
DOI:10.1016/S0957-4166(00)00389-X

Reference yield:

: 6893-65-8,20513-95-5,20513-96-6,34981-06-1,40429-51-4,110349-61-6
1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose

: 321868-67-1
2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-(6S)-yl-O-(S-methyl dithicarbonate)

Guidance literature:: Multi-step reaction with 2 steps

1.1: 83 percent / tetrahydrofuran / 20 °C

2.1: NaH / tetrahydrofuran; hexane / 0.25 h / 0 °C

2.2: tetrahydrofuran; hexane / 0.25 h / 0 °C

2.3: 93 percent / tetrahydrofuran; hexane / 0 - 20 °C

With sodium hydride; In tetrahydrofuran; hexane; 1.1: Substitution / 2.1: Metallation / 2.2: Addition / 2.3: Methylation;
DOI:10.1016/S0957-4166(00)00389-X