(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate

Base Information

• Chemical Name: (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate
• CAS No.: 1232133-61-7
• Molecular Formula: CF₃O₃S*C₁₆H₁₈IO
• Molecular Weight: 502.293
• Mol file: 1232133-61-7.mol

Synonyms:(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate

Chemical Property of (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate

There total 1 articles about (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

trifluorormethanesulfonic acid (1493-13-6) + 4-iodoanisol (529-28-2) + 1,3,5-trimethyl-benzene (108-67-8) → (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate (1232133-61-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 2h; Inert atmosphere; Sealed tube;

DOI:10.1016/j.tet.2017.03.055

Reference yield: 90.0%

4-indol-3-yl-butyric acid (133-32-4) + (2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate (1232133-61-7) → 4-(2-(2-methoxyphenyl)-1H-indol-3'-yl)butanoic acid

Guidance literature:

With palladium diacetate; In water; at 100 ℃; for 1h; regioselective reaction;

DOI:10.1002/asia.201601290

Reference yield: 79.0%

(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate (1232133-61-7) → mesityl(2-methoxyphenyl)iodonium hexafluoroarsenate(V)

Guidance literature:

(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate; In acetonitrile; for 0.0833333h;

With sodium hexafluoroarsenate; In water; acetonitrile; for 0.5h;

DOI:10.1021/ja305100g

upstream raw materials:

trifluorormethanesulfonic acid

4-iodoanisol

1,3,5-trimethyl-benzene

Downstream raw materials:

(3aR,8aR)-1-benzyl-3a-(2-methoxyphenyl)-8-methyl-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indol-2(1H)-one

2-bromoanisole

2-(2-methoxyphenyl)-1H-indole

diethyl [2-(methoxy)phenyl]phosphonate