Bis(4-carboxyphenyl)dimethylsilane

Base Information

• Chemical Name: Bis(4-carboxyphenyl)dimethylsilane
• CAS No.: 17003-01-9
• Molecular Formula: C16H16 O4 Si
• Molecular Weight: 300.386
• NSC Number: 179703
• DSSTox Substance ID: DTXSID10306767
• Nikkaji Number: J802.967I
• Wikidata: Q82054047
• ChEMBL ID: CHEMBL1337836
• Mol file: 17003-01-9.mol

Synonyms:17003-01-9;Bis(4-carboxyphenyl)dimethylsilane;NSC179703;4,4'-(dimethylsilanediyl)dibenzoic acid;4-[(4-carboxyphenyl)-dimethylsilyl]benzoic acid;NSC-179703;Benzoic acid,4,4'-dimethylsilylenebis- 4-[4-carboxyphenyl-dimethylsilyl]benzoicacid;NCIStruc1_000707;NCIStruc2_001712;SCHEMBL3482898;CHEMBL1337836;DTXSID10306767;CCG-38269;NCGC00014520;NCI179703;4,4'-(dimethylsilanediyl)dibenzoicacid;NCGC00014520-02;NCGC00097624-01;NCI60_001508;CS-0110935;4-[(4-carboxyphenyl)-dimethyl-silyl]benzoic acid

Chemical Property of Bis(4-carboxyphenyl)dimethylsilane

Chemical Property:

• Boiling Point: 446.3°Cat760mmHg
• Flash Point: 223.7°C
• Density: 1.25g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 300.08178552
• Heavy Atom Count: 21
• Complexity: 355

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C1=CC=C(C=C1)C(=O)O)C2=CC=C(C=C2)C(=O)O

Technology Process of Bis(4-carboxyphenyl)dimethylsilane

There total 7 articles about Bis(4-carboxyphenyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

di(4-cyanophenyl)dimethylsilane (17961-74-9) → 4,4′-(dimethylsilanediyl)bis-benzoic acid (17003-01-9)

Guidance literature:

With potassium hydroxide; In potassium hydroxide;

DOI:10.1021/jo50018a011

Reference yield: 63.0%

bis(4-methylphenyl)dimethylsilane (2097-02-1) → 4,4′-(dimethylsilanediyl)bis-benzoic acid (17003-01-9)

Guidance literature:

With potassium permanganate; In pyridine; water;

DOI:10.1021/jo50018a011

Reference yield:

para-bromotoluene (106-38-7) → 4,4′-(dimethylsilanediyl)bis-benzoic acid (17003-01-9)

Guidance literature:

Multi-step reaction with 2 steps

1: magnesium

2: aqueous KMnO₄

With potassium permanganate; magnesium;

DOI:10.1007/PL00012184

upstream raw materials:

(bis(4-bromophenyl)dimethylsilane)

bis(4-methylphenyl)dimethylsilane

di(4-cyanophenyl)dimethylsilane

para-bromotoluene

Downstream raw materials:

me2Si(ph-4-COOme)2

bis(4-hydroxymethylphenyl)dimethylsilane