bis(4-broMophenyl)diMethylsilane

Base Information

• Chemical Name: bis(4-broMophenyl)diMethylsilane
• CAS No.: 18419-48-2
• Molecular Formula: C14H14Br2Si
• Molecular Weight: 370.159
• Mol file: 18419-48-2.mol

Synonyms:bis(4-broMophenyl)diMethylsilane

Chemical Property of bis(4-broMophenyl)diMethylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 4.03420

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(4-broMophenyl)diMethylsilane

There total 8 articles about bis(4-broMophenyl)diMethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

(ph-4-Br)2SiCl2 (18030-47-2) → (bis(4-bromophenyl)dimethylsilane) (18419-48-2)

Guidance literature:

In not given;

Reference yield: 86.0%

1.4-dibromobenzene (106-37-6) + dimethylsilicon dichloride (75-78-5,30107-43-8) → (bis(4-bromophenyl)dimethylsilane) (18419-48-2)

Guidance literature:

1.4-dibromobenzene; With n-butyllithium; In diethyl ether; hexane; at -70 ℃;

dimethylsilicon dichloride; In hexane;

In hexane; Acidic conditions;

DOI:10.1016/j.jorganchem.2015.01.024

Reference yield: 70.0%

4-bromophenyllithium (22480-64-4) + dimethylsilicon dichloride (75-78-5,30107-43-8) → (bis(4-bromophenyl)dimethylsilane) (18419-48-2)

Guidance literature:

In diethyl ether; for 5h; Ambient temperature;

DOI:10.1016/0022-328X(95)05473-3

upstream raw materials:

1.4-dibromobenzene

dimethylsilicon dichloride

4-bromophenyllithium

ethylene dibromide

Downstream raw materials:

bis-(4-aminomethyl-phenyl)-dimethyl-silane

bis(p-phenylethynylphenyl)dimethylsilane

bis(4-(pyrazol-1-yl)phenyl)dimethylsilane

Refernces

• 1、 Tundidor-Camba, Alain,González-Henríquez, Carmen M.,Sarabia-Vallejos, Mauricio A.,Tagle, Luis H.,Hauyón, René A.,Sobarzo, Patricio A.,González, Alexis,Ortiz, Pablo A.,Maya, Eva M.,Terraza, Claudio A.. "Silylated oligomeric poly(ether-azomethine)s from monomers containing biphenyl moieties: Synthesis and characterization". . p. 1296 - 1312. Retrieved 2018.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF". Paragraph 0193; 0196. . Retrieved 2016/10/31.