Technology Process of (acetylacetonate)erbium(III)-2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin
There total 2 articles about (acetylacetonate)erbium(III)-2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
-
-
1005788-70-4
(acetylacetonate)erbium(III)-2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin
- Guidance literature:
-
(acetylacetonate)erbium(III)-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin;
With
bromine;
In
chloroform;
at 20 ℃;
With
pyridine;
In
chloroform;
at 20 ℃;
DOI:10.1021/jp9119183
-
-
1005788-70-4
(acetylacetonate)erbium(III)-2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin
- Guidance literature:
-
With
pyridine; sodium metabisulfite;
In
CHCl3;
to stirred soln. of Er(acac)-tetrakis(pentafluoro-Ph)porphyrin in CHCl3 added soln. of Br2 in CHCl3 for 15 min at room temp. and stirring continued for 1 h; soln. Py in CHCl3 added dropwise with stirring and then aq.soln. of Na-metabisulfite added; org. layer sepd., dried over anhydrous sodium sulfate and solvent evapd.at reduced pressure; compd. crystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/jp9119183
