3-(2-Furanyl)-2-propenal

Base Information

• Chemical Name: 3-(2-Furanyl)-2-propenal
• CAS No.: 623-30-3
• Molecular Formula: C7H6O2
• Molecular Weight: 122.123
• Hs Code.: 29321900
• European Community (EC) Number: 210-785-3
• DSSTox Substance ID: DTXSID40881153
• Nikkaji Number: J626.930C
• Wikidata: Q81981646
• Metabolomics Workbench ID: 45781
• Mol file: 623-30-3.mol

Synonyms:3-(2-Furanyl)-2-propenal;3-(2-Furyl)acrylaldehyde;3-(2-Furyl)-2-propenal;(2E)-3-(2-furyl)acrylaldehyde;(2E)-3-(furan-2-yl)prop-2-enal;(2z)-3-(2-furanyl)-2-propenal;alpha -furyl)propenal;beta -2-Furylacrolein;3-2-Furyl;Furfurylideneacetaldehyde;3-(alpha -Furyl)propenal;(Z)-3-(2-Furyl)propenal;SCHEMBL2562658;FEMA 2494;DTXSID40881153;(2E)-3-(2-Furyl)-2-propenal;(2Z)-3-(furan-2-yl)prop-2-enal;71277-14-0

Chemical Property of 3-(2-Furanyl)-2-propenal

Chemical Property:

• Appearance/Colour: Colorless to light yellow liquid
• Vapor Pressure: 0.0351mmHg at 25°C
• Melting Point: 49-55 ºC
• Refractive Index: 1.539
• Boiling Point: 241.9 °C at 760 mmHg
• Flash Point: 88.8 °C
• PSA: 30.21000
• Density: 1.104 g/cm³
• LogP: 1.49170
• Storage Temp.: 0-10°C
• Sensitive.: Air Sensitive
• Water Solubility.: insoluble
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 122.036779430
• Heavy Atom Count: 9
• Complexity: 118

Purity/Quality:

99%min ^*data from raw suppliers

3-(Furan-2-yl)acrylaldehyde ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-28-36/37/39-45-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=COC(=C1)C=CC=O
• Isomeric SMILES: C1=COC(=C1)/C=C\C=O

Technology Process of 3-(2-Furanyl)-2-propenal

There total 30 articles about 3-(2-Furanyl)-2-propenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

furfural (98-01-1) + triethylamine (121-44-8) → 3-furan-2-yl-propenal (623-30-3)

Guidance literature:

With chloro-trimethyl-silane; scandium tris(trifluoromethanesulfonate); In dichloromethane; at 0 - 20 ℃; for 24h; Sealed tube; Inert atmosphere;

DOI:10.3987/COM-13-S(S)98

Reference yield: 79.0%

C19H30O2S → 3-furan-2-yl-propenal (623-30-3)

Guidance literature:

With triethylsilane; In tetrahydrofuran; for 1h; Reagent/catalyst;

DOI:10.1021/cs5004917

Reference yield: 65.0%

(E)-3-(2-furanyl)-2-propen-1-ol (27393-97-1,79380-02-2) → 3-furan-2-yl-propenal (623-30-3)

Guidance literature:

With p-benzoquinone; In diethylene glycol dimethyl ether; at 120 ℃; for 19h;

DOI:10.1016/S0040-4039(00)97659-7

upstream raw materials:

furfural

acetaldehyde

3-ethoxy-3-[2]furyl-propionaldehyde diethylacetal

sodium acetate

Downstream raw materials:

2-furanacrolein phenylhydrazone

3-[2]furyl-acrylaldehyde-(3-nitro-phenylimine)

11t-[2]furyl-undeca-2t,4t,6t,8t,10-pentaenal

3-(tetrahydrofuran-2-yl)propan-1-ol

Refernces

• 1、 Gao, Yiqi,Tong, Xinli,Zhang, Haigang. "A selective oxidative valorization of biomass-derived furfural and ethanol with the supported gold catalysts". . p. 238 - 245. Retrieved 2019/06/18.
• 2、 Tong,Zhang, Zhenya,Gao, Yiqi,Zhang, Yue,Yu, Linhao,Li, Yongdan. "Selective carbon-chain increasing of renewable furfural utilizing oxidative condensation reaction catalyzed by mono-dispersed palladium oxide". . . Retrieved 2019/08/12.