bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone

Base Information

• Chemical Name: bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone
• CAS No.: 148240-46-4
• Molecular Formula: C₂₅H₂₀N₆S
• Molecular Weight: 436.54
• Mol file: 148240-46-4.mol

Synonyms:bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone

Chemical Property of bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone

There total 1 articles about bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenyl(pyridin-2-yl)methanone (91-02-1) + Thiocarbohydrazide (2231-57-4) → bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone (148240-46-4)

Guidance literature:

With acetic acid; In methanol; acetonitrile; at 65 ℃; for 24h;

Reference yield: 83.7%

copper(II) perchlorate hexahydrate + bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone (148240-46-4) → [Cu4(1,5-bis(2-benzoylpyridine)thiocarbohydrazone(-2H))2(H2O)2](ClO4)4

Guidance literature:

In methanol; chloroform; ligand in CHCl3 mixed with Cu salt (molar ratio 1:2) in MeOH; refluxed for 30 min; filtered; ppt. washed with MeOH and ether; dried in vac. over P4O10; elem. anal.;

DOI:10.1016/j.saa.2008.10.030

Reference yield: 64.0%

manganese(II) chloride tetrahydrate + bis[phenyl(2-pyridyl)methanone]thiocarbohydrazone (148240-46-4) → [Mn(1,5-bis(2-benzoylpyridine)thiocarbohydrazone)Cl2]?H2O

Guidance literature:

In methanol; chloroform; for 2h; Reflux;

DOI:10.1016/j.molstruc.2021.131125

upstream raw materials:

phenyl(pyridin-2-yl)methanone

Thiocarbohydrazide

Downstream raw materials:

(Cu₂Cl₂(C₅H₄NC(C₆H₅)NNCSNNC(C₆H₅)C₅H₄N))2