2-methyl-1-tributylstannyl cyclohexanol

Base Information

Chemical Name:2-methyl-1-tributylstannyl cyclohexanol
CAS No.:126300-46-7
Molecular Formula:C₁₉H₄₀OSn
Molecular Weight:403.236
Hs Code.:

Synonyms:2-methyl-1-tributylstannyl cyclohexanol

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Chemical Property of 2-methyl-1-tributylstannyl cyclohexanol

Chemical Property:

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Technology Process of 2-methyl-1-tributylstannyl cyclohexanol

There total 1 articles about 2-methyl-1-tributylstannyl cyclohexanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 27262-82-4
tributylstannylmagnesium chloride

: 583-60-8
2-Methylcyclohexanone

: 126300-46-7
2-methyl-1-tributylstannyl cyclohexanol

Guidance literature:: With water; In diethyl ether; dropwise addn. of soln. of carbonyl compd. in ether to soln. of Bu3SnMgCl in ether, equimolar amts. of educts, -50 to -40°C, stirring, 4h, warmed up to ambient temp., addn. of water, then reflux, 3h, under inert gas; fractional distn. (vac., bath temp.: 70°C); purity checked by HPLC;
DOI:10.1016/0022-328X(87)80020-7

Reference yield: 65.0%

: 126300-46-7
2-methyl-1-tributylstannyl cyclohexanol

: 103-71-9
phenyl isocyanate

: 136052-32-9
(C₄H₉)3SnC₆H₉(CH₃)OCONHC₆H₅

Guidance literature:: In pentane; byproducts: 1,3-diphenylurea; react. under an inert atmosphere; addn. of phenyl isocyanate soln. to Sn-compound in soln. at room temp. (molar ratio 2:1), stirred at reflux for 5h, pptn.; ppt. removed by filtration, cooled to -20°C overnight, pptn. of last traces of diphenylurea, solvent and unreacted isocyanate removed under reduced pressure;

Reference yield: 40.0%

: 937-63-3
p-Tolyl chlorothionoformate

: 126300-46-7
2-methyl-1-tributylstannyl cyclohexanol

: 100073-21-0
(C₄H₉)3SnC₆H₈(CH₃)

Guidance literature:: With sodium hydrogen sulfate; sulfuric acid; water; In pyridine; dichloromethane; byproducts: p-H3CC6H4OH; slow addn. of soln. of CH3PhOC(S)Cl in CH2Cl2 to cold (-20°C) soln. of alcohol in pyridine, 3h. 0°C, ice, extd. with CH2Cl2, treatment with H2SO4 (10%), NaHCO3 (10%), H2O; mixt. warmed up to 200°C, then thermolysis at 750°C; in N2, condensation of products in a dewar vessel (liquid N2), warmed up to ambient temp.; first reaction detected by HPLC and IR, purifn. of educt by chromy. (Florisil, pentane), purifn. checked by HPLC or GC;
DOI:10.1016/0022-328X(87)80020-7