(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Base Information

Chemical Name:(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc
CAS No.:573658-46-5
Molecular Formula:C₆₂H₇₁BN₄O₁₄Zn
Molecular Weight:1172.47
Hs Code.:

(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Synonyms:(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

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Chemical Property of (tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

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Technology Process of (tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

There total 2 articles about (tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 253604-41-0
(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 573658-46-5
(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: With triethylamine; bis-triphenylphosphine-palladium(II) chloride; In 1,2-dichloro-ethane; (N2); refluxed for 18 h; cooled to 20°C, Et2O and satd. aq. soln. of NaH2PO4 added, the org. layer sepd., washed (H2O and satd. aq. NaCl), evapd. (vac.), dissolved in Et2O, filtered (SiO2, Et2O), evapd. (vac.), recrystd. (CH2Cl2/hexane); elem. anal.;
DOI:10.1002/hlca.200490288

Reference yield: 33.0%

: 253604-41-0
(SP-4-2)-[[tetraethyl 4,4',4'',4'''-[10-bromo-21H,23H-porphine-5,15-diylbis(benzene-2,1,3-triyldioxy)]tetrakis(butanoato)]^(2-)-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾]zinc(II)

: 73183-34-3
bis(pinacol)diborane

: 573658-46-5
(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: With potassium acetate; bis-triphenylphosphine-palladium(II) chloride; In dimethyl sulfoxide; (N2); for 24 h at 80°C; cooled to 20°C, Et2O added, the org. layer sepd., washed with satd. aq. NaH2PO4 and satd. aq. NaCl, filtered (SiO2, Et2O), evapd. (vac.),flash-chromd. (SiO2-H, CHCl3/AcOEt), recrystd. (CH2Cl2/hexane);
DOI:10.1002/hlca.200490288

Reference yield: 63.0%

: 573658-46-5
(tetraethyl 4,4',4'',4'''-[[10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

: 583-55-1
1-Bromo-2-iodobenzene

: 573658-50-1
(tetraethyl 4,4',4'',4'''-[[10-(2-bromophenyl)porphyrin-5,15-diyl-κN(21),κN(22),κN(23),κN(24)]bis[benzene-2,1,3-triylbis(oxy)]]tetrabutanoato(2-))zinc

Guidance literature:: With caesium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; (N2); for 6 h at 110°C; cooled to 20°C, Et2O and satd. aq. soln. of NaH2PO4 added, the org. layer sepd., washed with H2O and satd. aq. NaCl; evapd. (vac.), flash-chromd. (SiO2-H, CHCl3/EtOAc);
DOI:10.1002/hlca.200490288