4-Chloro-N-allylaniline

Base Information

• Chemical Name: 4-Chloro-N-allylaniline
• CAS No.: 13519-80-7
• Molecular Formula: C9H10ClN
• Molecular Weight: 167.638
• Hs Code.: 2921420090
• Mol file: 13519-80-7.mol

Synonyms:Aniline,N-allyl-p-chloro- (8CI);Benzenamine, 4-chloro-N-2-propenyl- (9CI);N-Allyl-4-chloroaniline;N-Allyl-p-chloroaniline;NSC 73155;4-Chloro-N-(prop-2-en-1-yl)aniline;

Chemical Property of 4-Chloro-N-allylaniline

Chemical Property:

• Vapor Pressure: 0.0059mmHg at 25°C
• Refractive Index: 1.582
• Boiling Point: 272.9 °C at 760 mmHg
• PKA: 3.42±0.50(Predicted)
• Flash Point: 118.9 °C
• PSA: 12.03000
• Density: 1.125 g/cm³
• LogP: 3.01090

Purity/Quality:

99% ^*data from raw suppliers

4-CHLORO-N-(PROP-2-EN-1-YL)ANILINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Chloro-N-allylaniline

There total 23 articles about 4-Chloro-N-allylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

allyl-(4-chloro-phenyl)-carbamic acid tert-butyl ester → N-allyl-4-chloroaniline (13519-80-7)

Guidance literature:

With hydrogenchloride; water; at 20 ℃; for 15h;

DOI:10.1016/j.tetlet.2011.12.095

Reference yield: 90.0%

4-chloro-aniline (106-47-8) + allyl bromide (106-95-6) → N,N-diallyl-4-chlorobenzenamine (30438-94-9) + N-allyl-4-chloroaniline (13519-80-7)

Guidance literature:

With potassium fluoride on Celite; In acetonitrile; Reflux;

DOI:10.1016/j.tetlet.2009.09.156

Reference yield: 90.0%

4-chloro-aniline (106-47-8) + allyl pheny telluroxide (119803-83-7) → N-allyl-4-chloroaniline (13519-80-7)

Guidance literature:

at 65 ℃; for 6h;

DOI:10.1016/S0040-4039(00)80649-8

upstream raw materials:

allyl benzenesulfonate

4-chloro-aniline

allyl pheny telluroxide

allylmagnesium bromide

Downstream raw materials:

4-chloro-2-(prop-2-en-1-yl)aniline

4-chloro-aniline

N-allyl-4-chloro-2-iodoaniline

N-(2-allyl-4-chloro-phenyl)-acrylamide