(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

Base Information

Chemical Name:(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal
CAS No.:335455-28-2
Molecular Formula:C₂₈H₃₈O₂Si
Molecular Weight:434.694
Hs Code.:

Synonyms:(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

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Chemical Property of (6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

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Technology Process of (6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

There total 6 articles about (6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 335455-27-1
(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dien-1-ol

: 335455-28-2
(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

Guidance literature:: With oxalyl dichloride; In dichloromethane; dimethyl sulfoxide; at -78 ℃;
DOI:10.1021/ol015667k

Reference yield:

: 335455-23-7
(E)-7-iodo-6-methylhept-6-en-1-ol

: 335455-28-2
(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

Guidance literature:: Multi-step reaction with 5 steps

1.1: 90 percent / imidazole; DMAP / dimethylformamide

2.1: n-BuLi / diethyl ether / -78 °C

2.2: diethyl ether / -78 - 0 °C

3.1: 86 percent / KHMDS / tetrahydrofuran / -78 - 0 °C

4.1: 87 percent / PPTS / ethanol / 6 h / 23 °C

5.1: 86 percent / (COCl)2 / dimethylsulfoxide; CH₂Cl₂ / -78 °C

With 1H-imidazole; dmap; n-butyllithium; oxalyl dichloride; potassium hexamethylsilazane; pyridinium p-toluenesulfonate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1021/ol015667k

Reference yield:

: 335455-24-8
tert-butyl-(7-iodo-6-methyl-hept-6-enyloxy)-dimethyl-silane

: 335455-28-2
(6E,8Z)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methyl-deca-6,8-dienal

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-BuLi / diethyl ether / -78 °C

1.2: diethyl ether / -78 - 0 °C

2.1: 86 percent / KHMDS / tetrahydrofuran / -78 - 0 °C

3.1: 87 percent / PPTS / ethanol / 6 h / 23 °C

4.1: 86 percent / (COCl)2 / dimethylsulfoxide; CH₂Cl₂ / -78 °C

With n-butyllithium; oxalyl dichloride; potassium hexamethylsilazane; pyridinium p-toluenesulfonate; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol015667k