1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl

Base Information

• Chemical Name: 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl
• CAS No.: 406480-97-5
• Molecular Formula: C₃₈H₃₀N₄S₄
• Molecular Weight: 670.947
• Mol file: 406480-97-5.mol

Synonyms:1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl

Chemical Property of 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl

There total 6 articles about 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

phenylene-1,2-diisothiocyanate (71105-17-4) + 5-(tert-Butylamino)-3-methyl-4-phenyl-2-(phenylthio)thiazolium chloride → 13H-<1,3,5>thiodiazino<3,2-a,5,6-a'>bisbenzamidazole-13-thione (34858-80-5) + 3-(2-isothiocyanatophenyl)-1-methyl-2-phenyl-5-(phenylthio)imidazolium-4-thiolate (406480-96-4) + 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl (406480-97-5)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1002/hc.1093

Reference yield:

5-(tert-Butylamino)-3-methyl-4-phenyl-2-(phenylthio)thiazolium chloride + 3-(2-isothiocyanatophenyl)-1-methyl-2-phenyl-5-(phenylthio)imidazolium-4-thiolate (406480-96-4) → 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl (406480-97-5) + C43H39N5S5

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1002/hc.1093

Reference yield:

phenylene-1,2-diisothiocyanate (71105-17-4) → 1,2-bis[1-methyl-2-phenyl-5-(phenylthio)-4-thiolate-imidazolium-3-yl]phenyl (406480-97-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 68 percent / triethylamine / tetrahydrofuran / 2 h / 20 °C

2: triethylamine / tetrahydrofuran / 12 h / 20 °C

With triethylamine; In tetrahydrofuran;

DOI:10.1002/hc.1093

upstream raw materials:

phenylene-1,2-diisothiocyanate

3-(2-isothiocyanatophenyl)-1-methyl-2-phenyl-5-(phenylthio)imidazolium-4-thiolate