[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

Base Information

Chemical Name:[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]
CAS No.:704902-92-1
Molecular Formula:C₃₇H₃₇ClNNiOP
Molecular Weight:636.824
Hs Code.:

Synonyms:[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

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Chemical Property of [(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

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Technology Process of [(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

There total 1 articles about [(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 259266-36-9
2-[[2,6-bis(1-methylethyl)phenyl]amino]-2,4,6-cycloheptatrien-1-one

: 704902-92-1
[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

Guidance literature:: With triethylamine; In tetrahydrofuran; charging of Schlenk tube with (PPh3)2NiCl under Ar; addn. of THF; cooling to 0°C; addn. of NEt3 (excess); addn. of THF soln of 2-(2,6-diisopropyl)anilinotropone; gradually warming to room temp. for 5 h; filtration through Celite; removal of solvent in vac., recrystn. from toluene and pentane; elem. anal.;
DOI:10.1021/ja030634g

Reference yield: 48.0%

: 704902-92-1
[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

: sodium trimethoxyborohydride

: 704903-17-3
[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)(hydride)]

Guidance literature:: In diethyl ether; byproducts: B(OMe)3; charging of Schlenk tube with (PPh3)NiCl(2-(2,6-diisopropyl)anilinotropone) and NaHB(OMe)3 under Ar; cooling in an ice bath; addn. of Et2O; stirring for 4 h; filtration through florisil; removal of solvent in vac.; elem. anal.;
DOI:10.1021/ja030634g

Reference yield: 35.0%

: 704902-92-1
[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)chloride)]

: 1068-55-9
isopropylmagnesium chloride

: 704903-12-8
[(2-(2,6-diisopropyl)anilinotropone)nickel(triphenylphosphine)(isopropyl)]

Guidance literature:: In diethyl ether; charging of Schlenk tube with (PPh3)NiCl(2-(2,6-diisopropyl)anilinotropone) under Ar; addn. of ether; cooling to -78°C; addn. dropwise ofisopropylmagnesium chloride; stirring for 5 h; cold filtration through florisil; removal of solvent in vac. at -30°C; elem. anal.;
DOI:10.1021/ja030634g