(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

Base Information

Chemical Name:(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene
CAS No.:225113-10-0
Molecular Formula:C₂₈H₄₃NO₅Si
Molecular Weight:501.739
Hs Code.:

Synonyms:(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

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Chemical Property of (2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

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Technology Process of (2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

There total 4 articles about (2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (4S,6R)-4-{[((Z)-Buta-1,3-dienyl)oxy]-di-tert-butyl-silanyloxy}-6-((1S,2R)-2-phenyl-cyclohexyloxy)-5,6-dihydro-4H-[1,2]oxazine 2-oxide

: 225113-10-0
(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

Guidance literature:: With sodium hydrogencarbonate; In benzene; for 4h; Yield given; Heating;
DOI:10.1021/ja9829970

Reference yield:

: 134436-16-1
di-t-butylchlorosilane monotriflate

: 225113-10-0
(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, -23 deg C, 2.) THF, from -78 deg C to -25 deg C

2: 85 percent Spectr_. / CHCl₃; acetonitrile / 8 h / Ambient temperature

3: methylaluminum bis(2,6-diphenylphenoxide) / CH₂Cl₂ / 2 h / -50 °C

4: NaHCO₃ / benzene / 4 h / Heating

With n-butyllithium; sodium hydrogencarbonate; methylaluminium bis(2,6-diphenylphenoxide); In dichloromethane; chloroform; acetonitrile; benzene;
DOI:10.1021/ja9829970

Reference yield:

: 225113-08-6
[((Z)-Buta-1,3-dienyl)oxy]-di-tert-butyl-chloro-silane

: 225113-10-0
(2R,2aR,5aS,7R,8bR)-4,4-Di-tert-butyl-7-((1S,2R)-2-phenyl-cyclohexyloxy)-2-vinyl-hexahydro-1,3,5,8-tetraoxa-8a-aza-4-sila-acenaphthylene

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent Spectr_. / CHCl₃; acetonitrile / 8 h / Ambient temperature

2: methylaluminum bis(2,6-diphenylphenoxide) / CH₂Cl₂ / 2 h / -50 °C

3: NaHCO₃ / benzene / 4 h / Heating

With sodium hydrogencarbonate; methylaluminium bis(2,6-diphenylphenoxide); In dichloromethane; chloroform; acetonitrile; benzene;
DOI:10.1021/ja9829970