dibenzylphosphinic fluoride

Base Information

• Chemical Name: dibenzylphosphinic fluoride
• CAS No.: 51010-76-5
• Molecular Formula: C₁₄H₁₄FOP
• Molecular Weight: 248.237
• Mol file: 51010-76-5.mol

Synonyms:dibenzylphosphinic fluoride

Chemical Property of dibenzylphosphinic fluoride

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dibenzylphosphinic fluoride

There total 3 articles about dibenzylphosphinic fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

dibenzylphosphine oxide (13238-16-9) → dibenzylphosphinic fluoride (51010-76-5)

Guidance literature:

With Selectfluor; In acetonitrile; at 20 ℃; for 12h;

DOI:10.1021/acs.joc.6b01932

Reference yield: 32.0%

dibenzylphosphine oxide (13238-16-9) → dibenzylphosphinic acid (7369-51-9) + dibenzylphosphinic fluoride (51010-76-5)

Guidance literature:

With 4-(difluoroiodo)toluene; In chlorobenzene; at 60 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1016/j.tetlet.2018.06.044

Reference yield:

dibenzylphosphinic acid (7369-51-9) → dibenzylphosphinic fluoride (51010-76-5)

Guidance literature:

With dialkylaminosulfurtrifluoride; In diethyl ether; at 20 ℃; for 0.25h;

DOI:10.1055/s-1973-22302

upstream raw materials:

dibenzylphosphinic acid

dibenzylphosphine oxide