13238-16-9

Basic information

• Product Name: Phosphine oxide, bis(phenylmethyl)-
• CAS NO: 13238-16-9
• Molecular Formula: C14H15OP
• Molecular Weight: 230.246
• Mol File: 13238-16-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Phosphine oxide, bis(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine oxide, bis(phenylmethyl)-(13238-16-9)
• EPA Substance Registry System: Phosphine oxide, bis(phenylmethyl)-(13238-16-9)

Safety Data

• Hazardous Substances Data: 13238-16-9(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 1589-82-8 phenylmagnesium bromide 
• 762-04-9 phosphonic acid diethyl ester 
• 1809-19-4 dibutyl hydrogen phosphite 
• 6921-34-2 benzylmagnesium chloride 
• 20335-99-3 benzyl (phenyl)phosphine oxide 
• 24442-45-3 dibenzylphenylphosphane oxide 
• 1344732-73-5 benzylphenyl(2-pyridylmethyl)phosphine oxide 

Downstream Products

• 111527-19-6 3-dibenzylphosphinoyl-butyronitrile 
• 114888-93-6 3-dibenzylphosphinoyl-3-phenyl-propionic acid 
• 109516-37-2 3-dibenzylphosphinoyl-butyric acid 
• 7369-51-9 dibenzylphosphinic acid 
• 21187-16-6 dibenzyl-thiophosphinic acid 
• 56522-04-4 dibenzylphosphine 
• 109516-40-7 β-dibenzylphosphinoyl-isobutyric acid 
• 132623-98-4 1-dibenzylphosphinoyl-ethanol 
• 109595-52-0 dibenzyl(2-cyanoethyl)phosphine oxide 
• 109728-49-6 3-dibenzylphosphinoyl-propionic acid amide 
• 111527-20-9 β-dibenzylphosphinoyl-isobutyronitrile 
• 40203-71-2 1-benzyl-1-oxo-2-phenyl-octahydro-1λ⁵-phosphindol-3-one 
• 40203-69-8 1-benzyl-1-oxo-2-phenyl-hexahydro-1λ⁵-cyclopenta[b]phosphol-3-one 
• 52050-81-4 1t-benzyl-1c-oxo-2ξ-phenyl-(3ar,6at)-hexahydro-1λ⁵-cyclopenta[b]phosphol-3-one 

Relevant articles and documents

Reactions of elemental phoshorus and phosphine with electrophiles in superbasic systems: XIX. Formation of the C-P bond with participation of elemental phosphorus under microwave assistance

Microwave irradiation facilitates phosphorylation of aryl methyl chlorides and styrene with red phosphorus in the presence of strong bases and increases the yield of the main products, tertiary phosphine oxides. Nauka/Interperiodica 2007.

Highly Enantioselective Synthesis of Phosphorus-Containing ?-Benzosultams by Bifunctional Phosphonium Salt-Promoted Hydrophosphonylation

?-Benzosultam derivatives are potential drug candidates with diverse biological activities. A series of chiral ?-benzosultams bearing phosphorus functionalities was synthesized by catalytic asymmetric hydrophosphonylation in the presence of a bifunctional phosphonium salt catalyst. The desired hydrophosphonylation products were obtained in good yields with high enantioselectivities, and scale-up reactions and further derivations were successfully accomplished. Some control experiments were also conducted to elucidate the plausible reaction mechanism of this chemical transformation.

Microwave-assisted synthesis of α-aminophosphine oxides

Aminophosphine oxides and bis(phosphinoylmethyl)amines were synthesized by the microwave (MW)-assisted Kabachnik-Fields reaction of primary amines, paraformaldehyde and secondary phosphine oxides. The bisphosphines obtained after deoxygenation of the bis(phosphinoymethyl)amine derivatives were utilized in the synthesis of cyclic transition metal complexes.

Electrochemical Dehydrogenative Phosphorylation of Alcohols for the Synthesis of Organophosphinates

An eco-friendly and efficient method for the synthesis of organophosphinates via an electrochemical cross-dehydrogenative-coupling reaction between alcohols and secondary phosphine oxides has been developed. This electrochemical reaction was conducted at