methyl(2-methyl-1-naphthyl)phenylphosphine

Base Information

• Chemical Name: methyl(2-methyl-1-naphthyl)phenylphosphine
• CAS No.: 381716-95-6
• Molecular Formula: C₁₈H₁₇P
• Molecular Weight: 264.307
• Mol file: 381716-95-6.mol

Synonyms:methyl(2-methyl-1-naphthyl)phenylphosphine

Chemical Property of methyl(2-methyl-1-naphthyl)phenylphosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl(2-methyl-1-naphthyl)phenylphosphine

There total 3 articles about methyl(2-methyl-1-naphthyl)phenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(2-methyl-1-naphthyl)magnesium bromide (21450-90-8) + methyl(phenyl)chlorophosphine (15849-86-2,540513-01-7) → methyl(2-methyl-1-naphthyl)phenylphosphine (381716-95-6)

Guidance literature:

In tetrahydrofuran; diethyl ether; at -40 - 20 ℃; for 3h;

DOI:10.1021/jo015909u

Reference yield:

chloro(diisopropylamino)(phenyl)phosphine (20684-97-3) → methyl(2-methyl-1-naphthyl)phenylphosphine (381716-95-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 85 percent / diethyl ether / 1 h / -40 °C

2: HCl / diethyl ether / 1 h / 0 °C

3: 62 percent / diethyl ether; tetrahydrofuran / 3 h / -40 - 20 °C

With hydrogenchloride; In tetrahydrofuran; diethyl ether;

DOI:10.1021/jo015909u

Reference yield:

phenylmethyl(di-isopropylamino)phosphine → methyl(2-methyl-1-naphthyl)phenylphosphine (381716-95-6)

Guidance literature:

Multi-step reaction with 2 steps

1: HCl / diethyl ether / 1 h / 0 °C

2: 62 percent / diethyl ether; tetrahydrofuran / 3 h / -40 - 20 °C

With hydrogenchloride; In tetrahydrofuran; diethyl ether;

DOI:10.1021/jo015909u

upstream raw materials:

(2-methyl-1-naphthyl)magnesium bromide

methyl(phenyl)chlorophosphine

chloro(diisopropylamino)(phenyl)phosphine