pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate

Base Information

• Chemical Name: pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate
• CAS No.: 104350-99-4
• Molecular Formula: C₁₈H₁₃MnO₅P*F₆P
• Molecular Weight: 540.174
• Mol file: 104350-99-4.mol

Synonyms:pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate

Chemical Property of pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate

There total 1 articles about pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate (37504-44-2) + diphenyl(methyl)phosphine (1486-28-8) → pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate (104350-99-4)

Guidance literature:

In acetone; Mn(CO)5(CH3CN)PF6 dissolved in acetone together with 1.1 equiv. of phosphine, stirred at room temp. in the dark for 24 h under Ar; recrystn. from acetone/Et2O mixt.;

DOI:10.1021/om00152a010

Reference yield: 36.0%

sodium pentacarbonyl manganate (13859-41-1) + pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate (104350-99-4) → dimanganese decacarbonyl (10170-69-1) + Mn2(CO)8(methyldiphenylphosphine)2 (41133-30-6,63393-52-2) + Mn2(CO)9(methyldiphenylphosphine) (61943-58-6) + tetracarbonylhydrido(methyldiphenylphosphine)manganese (104350-80-3)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; addn. of 5 mL of 1E-2 M NaMn(CO)5 in THF to 5 mL of 1E-2 M Mn(CO)5PPh2MePF6 in THF under Ar at 22°C, react. time 5 min; not isolated; detected by IR and TLC;

DOI:10.1021/om00152a010

Reference yield: 35.0%

pentacarbonyl(methyldiphenylphosphine)manganese(I) hexafluorophosphate (104350-99-4) + sodium tetracarbonyl(triphenylphosphine)manganate(-I) (19457-74-0) → Mn2(CO)8(methyldiphenylphosphine)2 (41133-30-6,63393-52-2) + dimanganese octacarbonyl di-(triphenyl phosphine) (15279-67-1,10170-70-4) + tetracarbonylhydrido(triphenylphosphine)manganese (16925-29-4) + tetracarbonylhydrido(methyldiphenylphosphine)manganese (104350-80-3) + Mn2(CO)8(methyldiphenylphosphine)(triphenylphosphine) (109335-85-5)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; under Ar in THF soln. contg. 1E-2 M NaMn(CO)4PPh3 and 1E-2 M Mn(CO)5(PPh2Me)PF6 at 22°C, react. complete within 5 min; chromd. (SiO2, 4:1 v/v hexane/THF);

DOI:10.1021/om00152a010

upstream raw materials:

(acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate

diphenyl(methyl)phosphine

Downstream raw materials:

dimanganese decacarbonyl

Mn₂(CO)8(methyldiphenylphosphine)2

Mn₂(CO)9(methyldiphenylphosphine)

tetracarbonylhydrido(methyldiphenylphosphine)manganese