sodium tetracarbonyl(triphenylphosphine)manganate(-I)

Base Information

Chemical Name:sodium tetracarbonyl(triphenylphosphine)manganate(-I)
CAS No.:19457-74-0
Molecular Formula:C₂₂H₁₅MnO₄P*Na
Molecular Weight:452.26
Hs Code.:

Synonyms:sodium tetracarbonyl(triphenylphosphine)manganate(-I)

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Chemical Property of sodium tetracarbonyl(triphenylphosphine)manganate(-I)

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Technology Process of sodium tetracarbonyl(triphenylphosphine)manganate(-I)

There total 1 articles about sodium tetracarbonyl(triphenylphosphine)manganate(-I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15279-67-1,10170-70-4
dimanganese octacarbonyl di-(triphenyl phosphine)

: 19457-74-0
sodium tetracarbonyl(triphenylphosphine)manganate(-I)

Guidance literature:: With sodium amalgam; In tetrahydrofuran; Mn2(CO)8(PPh3)2 treated with sodioamalgam in THF for 1-2 h inder Ar; excess Hg and amalgam removed, mixt. filtered through Celite under Ar atmosphere;
DOI:10.1021/om00152a010

Reference yield: 100.0%

: 19457-74-0
sodium tetracarbonyl(triphenylphosphine)manganate(-I)

: 54039-46-2
pentacarbonyl(triphenylphosphine)manganese tetrafluoroborate

: 15279-67-1,10170-70-4
dimanganese octacarbonyl di-(triphenyl phosphine)

Guidance literature:: In tetrahydrofuran; byproducts: NaBF4, CO; Ar-atmosphere; 0.3 M TBAP, molar ratio Mn-complex cation : Mn-complex anion = 1:1; not isolated, detected by IR spectroscopy; Kinetics;