benzyl acetate-d₂

Base Information

• Chemical Name: benzyl acetate-d₂
• CAS No.: 108481-45-4
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 152.161
• Mol file: 108481-45-4.mol

Synonyms:benzyl acetate-d₂

Chemical Property of benzyl acetate-d₂

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzyl acetate-d₂

There total 5 articles about benzyl acetate-d₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Benzyl acetate (140-11-4) + dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane (145412-54-0) → benzyl acetate-d2 (108481-45-4)

Guidance literature:

Benzyl acetate; dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane; With triethylamine; In hexane; at 20 ℃; for 0.75h;

With deuteromethanol; water-d2; at 20 ℃; for 0.5h;

With dihydrogen peroxide; In methanol; at 20 ℃; for 1h; Further stages.;

DOI:10.1021/ja003507i

Reference yield: 47.0%

water-d2 (7789-20-0) + phenyl propargyl ketone (3623-15-2) → benzyl acetate-d2 (108481-45-4)

Guidance literature:

With sulfuric acid-d2; mercury dichloride; In diethyl ether; formation with D2O in ether within 48 hours, catalysis by traces of D2SO4 and HgCl2;;

Reference yield:

C29H38(2)H3N2O(1+)*CF3O3S(1-) + benzyl alcohol (100-51-6,185532-71-2) → benzyl acetate-d2 (108481-45-4)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane-d2; at 20 ℃; for 6h; Sealed tube; Glovebox; Inert atmosphere;

DOI:10.1002/anie.202010348

upstream raw materials:

(benzyloxy)acetylene

Benzyl acetate

dicyclohexyl(((trifluoromethyl)sulfonyl)oxy)borane

water-d2