4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

Base Information

Chemical Name:4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate
CAS No.:112321-09-2
Molecular Formula:C₂₃H₃₆O₃Si
Molecular Weight:388.623
Hs Code.:

Synonyms:4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

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Chemical Property of 4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

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Technology Process of 4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

There total 15 articles about 4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 98-88-4
benzoyl chloride

: 112320-97-5
4-methyl-5(R)-<1-((1,1-dimethylethyl)dimethylsilyloxy)-2(R)-propyl>-3-cyclohexen-1(S)-ol

: 112321-09-2
4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

Guidance literature:: With pyridine; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1021/jo00238a030

Reference yield:

: 112321-00-3,112419-70-2
2-((1R,5S)-5-Isopropenyl-2-methyl-cyclohex-2-enyl)-propan-1-ol

: 112321-09-2
4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

Guidance literature:: Multi-step reaction with 6 steps

1: 85 percent / N-bromosuccinimide / acetone / 0.25 h / 0 °C

2: O₃ / CH₂Cl₂ / 0.2 h / -78 °C

3: acetic anhydride, Et₃N, (N,N-dimethylamino)pyridine / CH₂Cl₂ / 16 h / 40 °C

4: 7 percent / zinc / ethanol; H₂O / 16 h / Heating

5: 83 percent / Et₃N, DMAP / CH₂Cl₂ / 15 h / Ambient temperature

6: 98 percent / pyridine / CH₂Cl₂ / 24 h / Ambient temperature

With pyridine; dmap; N-Bromosuccinimide; acetic anhydride; ozone; triethylamine; zinc; In ethanol; dichloromethane; water; acetone;
DOI:10.1021/jo00238a030

Reference yield:

: 112347-68-9
1-((3R,3aR,5R,7S,7aS)-7-Bromo-3,7a-dimethyl-octahydro-benzofuran-5-yl)-1-methoxy-eth-1-yl-hydroperoxide

: 112321-09-2
4-methyl-5(R)-1<1-(((1-dimethylethyl)dimethylsilyl)oxy)-2(R)-propyl>-3-cyclohexen-1(S)-yl benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: acetic anhydride, Et₃N, (N,N-dimethylamino)pyridine / CH₂Cl₂ / 16 h / 40 °C

2: 7 percent / zinc / ethanol; H₂O / 16 h / Heating

3: 83 percent / Et₃N, DMAP / CH₂Cl₂ / 15 h / Ambient temperature

4: 98 percent / pyridine / CH₂Cl₂ / 24 h / Ambient temperature

With pyridine; dmap; acetic anhydride; triethylamine; zinc; In ethanol; dichloromethane; water;
DOI:10.1021/jo00238a030