(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

Base Information

Chemical Name:(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal
CAS No.:216572-81-5
Molecular Formula:C₁₆H₂₃BrO₂Si
Molecular Weight:355.347
Hs Code.:

Synonyms:(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

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Chemical Property of (Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

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Technology Process of (Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

There total 6 articles about (Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 52753-91-0,132316-45-1
(E)-methyl 3-(2-formylphenyl)acrylate

: 216572-81-5
(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

Guidance literature:: Multi-step reaction with 6 steps

1: 55 percent / NaBH₄ / methanol; H₂O / 2 h / 0 °C

2: 98 percent / dimethylformamide / 0.25 h / Ambient temperature

3: DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

4: PDC, mol. sieves 4A / CH₂Cl₂ / 1 h / Ambient temperature

5: Br₂ / CH₂Cl₂ / 0 °C

6: Et₃N / 2 h / Ambient temperature

With sodium tetrahydroborate; dipyridinium dichromate; 4 A molecular sieve; bromine; diisobutylaluminium hydride; triethylamine; In methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)01834-6

Reference yield:

: 216572-78-0
3-(2-hydroxymethylphenyl)acrylic acid methyl ester

: 216572-81-5
(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

Guidance literature:: Multi-step reaction with 5 steps

1: 98 percent / dimethylformamide / 0.25 h / Ambient temperature

2: DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

3: PDC, mol. sieves 4A / CH₂Cl₂ / 1 h / Ambient temperature

4: Br₂ / CH₂Cl₂ / 0 °C

5: Et₃N / 2 h / Ambient temperature

With dipyridinium dichromate; 4 A molecular sieve; bromine; diisobutylaluminium hydride; triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)01834-6

Reference yield:

: 216572-80-4
(E)-3-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

: 216572-81-5
(Z)-2-Bromo-3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-propenal

Guidance literature:: Multi-step reaction with 2 steps

1: Br₂ / CH₂Cl₂ / 0 °C

2: Et₃N / 2 h / Ambient temperature

With bromine; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(98)01834-6