benzhydrylzirconocene methoxide

Base Information

• Chemical Name: benzhydrylzirconocene methoxide
• CAS No.: 100909-18-0
• Molecular Formula: C₂₄H₂₄OZr
• Molecular Weight: 419.678
• Mol file: 100909-18-0.mol

Synonyms:benzhydrylzirconocene methoxide

Chemical Property of benzhydrylzirconocene methoxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzhydrylzirconocene methoxide

There total 2 articles about benzhydrylzirconocene methoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

Schwartz's reagent + (C5H5)2Zr(Cl)C(C6H5)2OCH3 (100909-17-9) → zirconocene dichloride (1291-32-3) + (η5-C5H5)2ZrCl(OMe) + benzhydrylzirconocene chloride (85959-82-6) + benzhydrylzirconocene methoxide (100909-18-0)

Guidance literature:

In benzene-d6; (Cp2Zr(H)Cl)x placed in an NMR tube and suspended with a soln. of Cp2Zr(Cl)CPh2OCH3 in benzene-d6; mixt. heated at 55°C for 7 h;; not isolated; reaction followed by NMR spectroscopy;;

DOI:10.1021/ja00269a021

Reference yield: 5.0%

bis(cyclopentadienyl)dihydrozirconium (37342-98-6) + (C5H5)2Zr(Cl)C(C6H5)2OCH3 (100909-17-9) → zirconocene dichloride (1291-32-3) + (η5-C5H5)2ZrCl(OMe) + benzhydrylzirconocene chloride (85959-82-6) + benzhydrylzirconocene methoxide (100909-18-0)

Guidance literature:

In benzene-d6; (Cp2ZrH2) placed in NMR tube and suspended with a soln. of Cp2Zr(Cl)CPh2OCH3 in benzene-d6; mixt. heated at 55°C for 2 h;; not isolated; react. followed by NMR spectroscopy;;

DOI:10.1021/ja00269a021

upstream raw materials:

(C₅H₅)2Zr(Cl)C(C₆H₅)2OCH₃

bis(cyclopentadienyl)dihydrozirconium