benzhydrylzirconocene chloride

Base Information

Chemical Name:benzhydrylzirconocene chloride
CAS No.:85959-82-6
Molecular Formula:C₂₃H₂₁ClZr
Molecular Weight:424.097
Hs Code.:

Synonyms:benzhydrylzirconocene chloride

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Chemical Property of benzhydrylzirconocene chloride

Chemical Property:

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Technology Process of benzhydrylzirconocene chloride

There total 3 articles about benzhydrylzirconocene chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 1291-32-3
zirconocene dichloride

: 101-81-5
Diphenylmethane

: 85959-82-6
benzhydrylzirconocene chloride

Guidance literature:: With n-C₄H₉Li; In tetrahydrofuran; hexane; a soln. of CH2Ph2 in THF was slowly treated at room temp. with soln. of n-C4H9Li in hexane; after the mixt. was stirred 2 h, it was transferred slowly into a stirred soln. of Cp2ZrCl2 in THF; mixt. stirred overnight;; evapd.; residue extd. twice with pentane; extract cooled to -15°C, crystd. at -15°C and then at -30°C; elem. anal.;;
DOI:10.1021/ja00269a021

Reference yield: 20.0%

: Schwartz's reagent

: 100909-17-9
(C₅H₅)2Zr(Cl)C(C₆H₅)2OCH₃

: 1291-32-3
zirconocene dichloride

: (η5-C5H5)2ZrCl(OMe)

: 85959-82-6
benzhydrylzirconocene chloride

: 100909-18-0
benzhydrylzirconocene methoxide

Guidance literature:: In benzene-d6; (Cp2Zr(H)Cl)x placed in an NMR tube and suspended with a soln. of Cp2Zr(Cl)CPh2OCH3 in benzene-d6; mixt. heated at 55°C for 7 h;; not isolated; reaction followed by NMR spectroscopy;;
DOI:10.1021/ja00269a021

Reference yield: 5.0%

: 37342-98-6
bis(cyclopentadienyl)dihydrozirconium

: 100909-17-9
(C₅H₅)2Zr(Cl)C(C₆H₅)2OCH₃

: 1291-32-3
zirconocene dichloride

: (η5-C5H5)2ZrCl(OMe)

: 85959-82-6
benzhydrylzirconocene chloride

: 100909-18-0
benzhydrylzirconocene methoxide

Guidance literature:: In benzene-d6; (Cp2ZrH2) placed in NMR tube and suspended with a soln. of Cp2Zr(Cl)CPh2OCH3 in benzene-d6; mixt. heated at 55°C for 2 h;; not isolated; react. followed by NMR spectroscopy;;
DOI:10.1021/ja00269a021